The decoupling and enhancement of both Seebeck coefficient and electrical conductivity were achieved by constructing the c-axis preferentially oriented nanoscale Sb(2)Te(3) film on monolayer graphene. The external graphene layer provided a highway for charge carriers, which were stored in the thicker binary telluride film, due to the extremely high mobility.
Thermoelectric power waves, where multiwalled carbon
nanotubes
coated with cyclotrimethylene trinitramine (MWCNT/TNA) directly convert
chemical energy to electricity, have received considerable attention
recently. However, the low Seebeck coefficient of carbon nanotubes
has been regarded as a hurdle to increasing the electrical potential.
Here, we present Sb2Te3-coated MWCNT arrays
prepared by a sputtering method. An analytical model predicts an increase
in Seebeck coefficient of the annular multishell structure by ∼75%.
The heterostructure coupled with exothermic chemical reaction of TNA
demonstrates an increase in peak electrical potential of 175% (∼198
mV), compared with typical outputs of bare MWCNT/TNA (∼72 mV).
A serial connection of two repeating units increased the peak potential
by up to 406 mV.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.