Dedication: One of Alan Sargeson’s great abilities was to seek out knowledge on topics of which he was not the master from those people with the expertise. This led occasionally to publications with a ‘cricket team’ of authors but with a rich brew of information, often international. Alan also insisted that all authors were equal since, without any one, the paper would not be what it was. Hence, he endeavoured to pursue the policy, difficult to maintain over a period where an obsession with absurdities such as the order of authors and point-scoring based on meaningless publication indices became so important in the maintenance of research, of listing authors simply in alphabetical order. In describing work begun while he was still with us, we have attempted to adhere to his principles. Analysis of a body of crystallographic information concerning metal(ii) and metal(iii) complexes of macrobicyclic hexamine ligands and some of their derivatives provides evidence for the action of a variety of intermolecular forces within the lattices. Hydrogen bonding is universal and its forms depend strongly upon the oxidation state and the particular nature of the metal ion bound to the macrobicycle. The introduction of both aliphatic and aromatic substituents leads to lattices in which these substituents associate, although, in the case of aromatic substituents, this is not necessarily a consequence of ‘π-stacking’, despite the fact that the aromatic ring planes form parallel arrays. At least in the case of CoIII, stable enantiomers of the complexes can be obtained, and in {Δ-(+)589-[Co{(NH3)(CH3)sar}]}2Cl2(C6(CO2)6)·26H2O (sar = 3,6,10,13,16,19-hexa-azabicyclo[6.6.6]icosane), the benzene hexacarboxylate anion adopts a chiral conformation in the presence of the optically active cation.

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We investigate the sub-20nm level scalability of STT-MRAM cells possessing perpendicular magnetization induced from the interface of free layer (FL) and MgO tunnel barrier. We demonstrate that the MTJs utilizing dual interfaces of FL and MgO exhibit enhanced scalability with high thermal stability and low switching current, compared with the MTJs with a single interface. As thermal stability factor (') varies as a function of MTJ dimension, MTJs with dual interfaces show ' over 60 at 20nm node, while MTJs of single interface show ' around 33. MTJs with dual interface also exhibit lower switching current per thermal stability (Ic/'), ~1/2 level of single interface MTJs.

Structural studies have confirmed that it is possible to exploit the relatively low nucleophilicity of the “external” amino substituents on the CoIII complex of 1,8‐diaminosarcophagine (“sarcophagine” = sar = 3,6,10,13,16,19‐hexaazabicyclo[6.6.6]icosane) in acylation and alkylation reactions leading to a variety of functionalized cage amine complexes. With the appropriate choice of solvent, all these reactions can be conducted with high efficiency, and the new complexes display properties foreshadowing the application of cage systems in, for example, electroactive polymers.

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