One of the most important elements of the primary protection of concrete structures against chemical aggression is the correct choice of the type of cement. Specialists have done a lot of work to clarify the comparative stability of various types of cement systems in aggressive media containing various aggressive components [1-3]. Resistant cements for certain types of corrosion are known, but there is no complete concept of their choice. This causes difficulties in choosing the type of cement for specific types of corrosion in organic media, for complex types of corrosion, when the application of empirical approaches is unsuitable. This work is devoted to this issue.

A nature of the forces, which act between the concrete cement matrix and entrained mineral particles (ground additives, fine and coarse additives), has been considered. It has been shown that the adhesion between them is attributable to the forces of different nature. The strongest adhesion between the particles of the hydrated binding material and mineral additives occurs, when materials, which react with calcium hydrate of the pore fluid, are used. The latter includes glassy wollastonite, which is part of granulated blast furnace slag. Even at a temperature of 25 °C, an aggressive interaction between them is observed and firm chemical bonds occur. In such case, the dissociation energy of such bonds ranges from 400 to 500 kJ per bond. Between materials, such as crystalline wollastonite and the concrete cement matrix, there is an epitaxial coalescence of its basal surfaces and tobermorite calcium hydrosilicates formed by the interaction of the binder with water. A direct contact is required between the reacting surfaces for such interaction. This is implemented by virtue of the bond, which is attributable to contraction forces resulting from shrinkage strains of the hydrated particles in the concrete cement matrix. Internal strains of the cement that are attributable to contraction, shrinkage, and carbonization of hydrated compounds result in the cement sheath contracting around the aggregate grains and steel reinforcement. Internal strains of the cement stone can be calculated using the Lame equation. We have reviewed the role of the factors, which are most critical for contraction of the cement ring around coarse particles of the aggregate and for stress-strain properties of artificial conglomerates, which have different composition and purpose.

The study showed that in order to accelerate the hydration of inorganic binders it is necessary to use additives of such electrolytes that increase the concentration of calcium ions in the liquid phase of the cement suspension. Electrolytes (soda ash, sodium and potassium hydroxides), precipitating calcium ions in the liquid phase, promote their exit from the "shut-off" layer of hydration products. In this paper, we studied the additives – electrolytes – as regulators of the setting time of fine-grained and porous concrete. To increase the activity of the additive as a concrete mixtures setting time regulator, acidic varieties were used instead of main salts. The studied additives – electrolytes – draw practical interest, as their usage in production of foam concrete and fine-grained concrete lets accelerate hardening of products and speed up reuse of mould.

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