Communication and interaction with machines are changing our ways of life. However, developing an acoustic interface that simultaneously features waterproofness, wearability, high fidelity, and high accuracy for human–machine interaction remains a grand challenge. Herein, a waterproof acoustic sensor (WAS) as a wearable translation interface to communicate with machines is reported. Owing to the sound‐response ability of internal microparticles, the WAS holds a significantly broad frequency response range of 0.1–20 kHz, covering almost the entire human audible range. The WAS is stable against human perspiration, shows omnidirectional response, and displays an excellent frequency detection resolution of 0.0001 kHz. With a collection of compelling features, the WAS can serve as a wearable acoustic human–machine interface and a high‐fidelity auditory platform for music recording. Moreover, the WAS‐based acoustic interface holds a remarkable 98% accuracy for speech recognition with the assistance of an artificial intelligence algorithm. Finally, the WAS‐based acoustic interface demonstrates speaker verification and identification for implementation in highly secure biometric authentication systems and wireless control of an intelligent car using speech recognition. Such a WAS‐based acoustic interface represents the advancement of high‐fidelity translation platforms for human–machine interactions toward practical applications, including the Internet of Things, assistive technology, and intelligent recognition systems.
Offshore oil spills, industrial oily wastewater, and domestic oil pollution are some of the most serious global challenges, leading environmental causes of morbidity and mortality. Nanofiber membrane materials manufactured via...
NiWO4 microflowers with a large surface area up to 79.77 m2·g–1 are synthesized in situ via a facile coprecipitation method. The NiWO4 microflowers are further decorated with multi-walled carbon nanotubes (MWCNTs) and assembled to form composites for NH3 detection. The as-fabricated composite exhibits an excellent NH3 sensing response/recovery time (53 s/177 s) at a temperature of 460 °C, which is a 10-fold enhancement compared to that of pristine NiWO4. It also demonstrates a low detection limit of 50 ppm; the improved sensing performance is attributed to the porous structure of the material, the large specific surface area, and the p–n heterojunction formed between the MWNTs and NiWO4. The gas sensitivity of the sensor based on daisy-like NiWO4/MWCNTs shows that the sensor based on 10 mol % (MWN10) has the best gas sensitivity, with a sensitivity of 13.07 to 50 ppm NH3 at room temperature and a detection lower limit of 20 ppm. NH3, CO2, NO2, SO2, CO, and CH4 are used as typical target gases to construct the NiWO4/MWCNTs gas-sensitive material and study the research method combining density functional theory calculations and experiments. By calculating the morphology and structure of the gas-sensitive material NiWO4(110), the MWCNT load samples, the vacancy defects, and the influence law and internal mechanism of gas sensitivity were described.
Water pollution is one of the leading causes of death and disease worldwide, yet mitigating it remains a challenge. This paper presents an efficient new strategy for the processing of wastewater utilizing an accessible redox reaction with MoSe 2 nanoflowers, which shows a strong oxidizing ability and permits the decomposition of dye molecules in dark environments without the need for an external power source. This reaction can treat wastewater at a decomposition rate above 0.077 min −1 , even when interacting with organic pollutants at concentrations up to 1500 ppm. Theoretical calculations by Dmol 3 simulation elucidates that the reactions proceed spontaneously, and the kinetic constant (k obs ) for this redox reaction with 10 ppm RhB dye is 0.53 min −1 , which is 65 times faster than the titanium dioxide photocatalytic wastewater treatment. More importantly, the residual waste solution can be further utilized as a precursor to reconstruct the MoSe 2 nanoflowers. To demonstrate the effectiveness and reusability, the treated effluent is directly used as the sole source of irrigated water for plants with no adverse effect. This method offers an eco-friendly and more accessible way to treat industrial wastewater with zero-discharge.
Fiber-based electronics technology has been making significant strides towards applicable emergence into many fields. One such field is the use of fiber-based electronics in the development of smart textiles. Here, we report the use of stretchable styrene-ethylene-butylenestyrene (SEBS) fibers as a conductive substrate to simultaneously load Au nanowire and Prussian blue (PB) as biosensing interfaces. Accordingly, due to the synergistic catalytic effect between Au nanowire and Prussian blue, the as-obtained flexible PB/Au fibers can not only show the potential as wearable biosensors but also serve as high-performance peroxidase-like nanozymes. The functional fibers can be used for colorimetric detection of H 2 O 2 and uric acid, exhibiting satisfactory sensitivity and selectivity in serum sample analysis. The flexible PB/Au fibers represent a new form of Peroxidase-like nanozymes, which could open doors to various wearable biosensing applications.
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