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The construction materials utilized in the building sector have accounted for a large amount of natural resource and energy consumption. Green building, which has developed over three decades, can be regarded as a management and technical approach for building and construction sectors to achieve resource and energy sustainability in building sectors. Therefore, the development and deployment of green construction materials play an important role in the green building field due to the contribution of sustainable resources and energy. To realize the barriers of energy and resources utilization on green building, the development trend, application, and some case studies on wall materials and thermal insulation materials are described. A summary of plant fibers, recycled wastes, and photochromic glass is developed to show applications of green construction materials, which contributes to sustainable development. The challenges and barriers from business, technical, and policy aspects are also reviewed. Finally, perspectives and prospects of green construction material life-cycle framework are illustrated. This paper presents a snapshot review of the importance of wall materials and thermal insulation materials from the point of view of energy and resources consumption.