We report on the epitaxial growth of wide-band-gap cubic-phase MgxZn1−xO thin films on Si(100) by pulsed-laser deposition and fabrication of oxide-semiconductor-based ultraviolet photodetectors. The challenges of large lattice and thermal expansion mismatch between Si and MgxZn1−xO have been overcome by using a thin SrTiO3 buffer layer. The heteroepitaxy of cubic-phase MgxZn1−xO on Si was established with epitaxial relationship of MgxZn1−xO(100)//SrTiO3(100)//Si(100) and MgxZn1−xO[100]//SrTiO3[100]//Si[110]. The minimum yield of the Rutherford backscattering ion channeling in MgxZn1−xO layer was only 4%, indicating good crystalline quality of the film. Smooth surface morphology with rms roughness of 0.6 nm was observed using atomic force microscopy. Photodetectors fabricated on Mg0.68Zn0.32O/SrTiO3/Si show peak photoresponse at 225 nm, which is in the deep UV region.
The phenomenon of persistent photoconductivity is elusive and has not been addressed to an extent to attract attention both in micro and nanoscale devices due to unavailability of clear material systems and device configurations capable of providing comprehensive information. In this work, we have employed a nanostructured (nanowire diameter 30–65 nm and 5 μm in length) ZnO-based metal–semiconductor–metal photoconductor device in order to study the origin of persistent photoconductivity. The current–voltage measurements were carried with and without UV illumination under different oxygen levels. The photoresponse measurements indicated a persistent conductivity trend for depleted oxygen conditions. The persistent conductivity phenomenon is explained on the theoretical model that proposes the change of a neutral anion vacancy to a charged state.
Over the past few years there has been sustained interest in the synthesis, characterization and application of cadmium sulphide (CdS) nanostructures such as nanoparticles, nanowires, nanobelts, nanospheres. The history of CdS, more recent advances in the chemistry and synthesis of CdS nanostructures, and their application as nanoscale devices in diverse technology areas from electronics to targeted drug delivery is described. Although the focus is on CdS, the review provides an excellent overview of the materials, methods, processes and promising solutions that are emerging.
Pulsed-laser-deposited polycrystalline/amorphous films of mixed-valent manganites [La0.7Ca0.3MnO3 (LCMO), La0.5Sr0.5MnO3 (LSMO), La0.5Ba0.5MnO3 (LBMO), and (La0.6Pr0.4)0.67Ca0.33MnO3 (LPCMO)] grown at low temperature (450 °C) on single crystal (001) silicon substrate are evaluated for uncooled bolometric applications. It is shown that the temperature coefficient of resistance (TCR) and electrical noise (Sv) depend on the chemical composition. The optimum performance is found for LCMO with TCR of ∼7% K−1 and spectral noise ∼8.9×10−13 V2/Hz. In LBMO and LSMO the noise is much lower, but so is the TCR (1.5%–2% K−1). In LPCMO the TCR is high (∼10% K−1) and the noise is as well.
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