It is proposed to apply the direct measurement of spontaneous polarization using triangular waves to ferroelectric liquid crystals. The use of the triangular waves allows us to easily subtract the background contribution due to the conductive and the capacitive current and to accurately determine the spontaneous polarization, since a bump due to the polarization realignment appears on a straight base line. Moreover, the experiment with pulsed triangular waves clearly reveals no existence of the threshold voltage for deforming the helix and some characteristic properties of the dynamic reaction of the helix to the field applied.
Epitaxial graphene on Si (GOS) using a heteroepitaxy of 3C-SiC/Si has attracted recent attention owing to its capability to fuse graphene with Si-based electronics. We demonstrate that the stacking, interface structure, and hence, electronic properties of GOS can be controlled by tuning the surface termination of 3C-SiC(111)/Si, with a proper choice of Si substrate and SiC growth conditions. On the Si-terminated 3C-SiC(111)/Si(111) surface, GOS is Bernal-stacked with a band splitting, while on the C-terminated 3C-SiC(111)/Si(110) surface, GOS is turbostratically stacked without a band splitting. This work enables us to precisely control the electronic properties of GOS for forthcoming devices.
Recently, circularly polarized luminescence (CPL)-active systems have become a very hot and interesting subject in chirality- and optics-related areas. The CPL-active systems are usually available by two approaches: covalently combining a luminescent centre to chiral motif or associating the guest of luminescent probe to a chiral host. However, all the chiral components in CPL materials were organic, although the luminescent components were alternatively organics or inorganics. Herein, the first totally inorganic CPL-active system by "luminescent guest-chiral host" strategy is proposed. Luminescent sub-10 nm lanthanide oxides (Eu O or Tb O ) nanoparticles (guests) were encapsulated into chiral non-helical SiO nanofibres (host) through calcination of chiral SiO hybrid nanofibres, trapping Eu (or Tb ). These lanthanide oxides display circular dichroism (CD) optical activity in the ultraviolet wavelength and CPL signals around at 615 nm for Eu and 545 nm for Tb . This work has implications for inorganic-based CPL-active systems by incorporation of various luminescent guests within chiral inorganic hosts.
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