Oxidation of the reductants is a dominant factor in the electroless deposition process. In order to obtain fundamental knowledge about the reaction mechanism of reductant oxidation for more precise control of the solid-liquid interface in this process, we have attempted to characterize the behavior of reductants adsorbed on Cu surface by using plasmon antenna enhanced Raman scattering. The concentric-patterned antenna coated with Cu, which consisted of a dimple array with single hole or a single hole with coaxial dimples, was designed by Finite Difference Time Domain (FDTD) calculation to enhance the electric field by focusing surface plasmons. By using this antenna and comparing the spectra to the results of Density Functional Theory (DFT) calculations, Raman peaks of adsorbed reductants on Cu were identified. Furthermore, we examined the conformation of adsorbed reductants by DFT calculation of the adsorption model of reductants on fcc-Cu(111) surface. As a result, the nature of reductant adsorption on Cu surface has been investigated from a computational point of view and an experimental point of view, and such in-situ characterization will be useful for analysis of a variety of systems at solid-liquid interface.

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Fabrication of Co-Pt and Fe-Pt ferromagnetic nanodot arrays for the application of ultra-high density bit patterned media (BPM) by electrochemical processes was described. In order to form patterned substrates for nanodot arrays with the density higher than 1 Tbit/inch 2 , electron beam lithography technique was employed. Nanopatterns with 25 nm and 18 nm pitch, which correspond to 1 and 2 Tbit/inch 2 were successfully formed by optimizing the condition of the lithography process, and Co-Pt and Fe-Pt with relatively high coercivity of 4.8 kOe and 10.3 kOe were formed by electrodeposition. By utilizing the nanopatterned substrates, Co-Pt and Fe-Pt nanodot arrays with 25 nm and 35 nm pitch were uniformly formed. These results demonstrate capability of the electrochemical processes for fabricating magnetic nanodot arrays with Tbit-level density.

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