Efficiently utilization of rice husk ash (RHA) and waste sludge from cutting glass manufacturer (WSG) as additives to pottery clay would yield positive economic impacts, such as more friendly industrial ecosystems. In this study, The RHA and WSH were used as additives to Angthong pottery clay (APC) and casting and fired properties were examined. Two sets of sample with a mixture consisting of 60% APC, 20% RHA, and 20% WSG (CRG formula) and non-added clay (C100 formula) were prepared by slip casting technique. Samples were fired at temperature 900 °C and 1100°C; then the viscosity of slurry, linear shrinkage, water adsorption, and 3-point bending strength were measured. The results showed that the optimum viscosity for slip casting of CRG and C100 were 1638 cP and 983 cP, respectively. The water adsorptions of all samples decrease while their shrinkage and strength increase with temperature. At 900°C, the water adsorption and the strength of CRG were 32% and 1184 psi, respectively. Comparatively, CRG’s water absorption was 1.5 times higher than C100’s, while their mechanical strength was insignificantly different. This due to the RHA behaves as pore forming and the WSG promotes the sintering of samples.
Lime mud from a pulp mill was used as an additive in brick clay from the southern part of Thailand. It was mixed with the clay from Cha-Aud district, Nakorn Sithammarat province. The chemical composition of lime mud and the clay was characterised by X-ray fluorescence (XRF), and the mineralogical composition was measured by X-ray diffraction (XRD). The particle size distribution was also measured. The main composition of lime mud is CaO, and Cha-Aud clay consists of SiO2 and Al2O3 as major oxides. The lime mud contains calcite as a major phase when Cha-Aud clay is constituted by quartz, kaolinite, illite and goethite. Particle size distribution of lime mud is in the range of 1-50 μm. After the lime mud was neutralized using hydrochloric acid, it was mixed with Cha-Aud clay at 10 wt%. Samples with and without lime mud were sintered at 700, 800, 900 and 1000°C for 1 hour. The results showed that lime mud can be used as an additive in brick clay. Both types of samples were similar in terms of physical properties when their linear firing shrinkage, water absorption and flexural strength were in the same range.
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