1, 1:9, 9:1, 2:3 dan 3:2, 5.37, 13.93, 8

The aim of this paper was to investigate the effects of cross-linked reaction on physicochemical properties of chitosan film by using genipin as cross-linker agent. Series of chitosan film samples with different amount concentration of genipin loaded (0-3 wt %) were prepared and characterized. The physicochemical properties of films were evaluated by Fourier Transform Infra-red (FTIR), UV-vis spectroscopy, Oxygen Transmission Rate (OTR), Scanning Electron Microscopy (SEM), water vapour and tensile test. The cross-linking reaction had affected on colour changing of chitosan film samples from light yellow to dark blue in line with the increasing of genipin concentration. Thus, UV-vis spectroscopy on the cross-linked samples showed the absorbance value at 600 nm wavelength due to genipin content. FTIR observation on cross-linked film samples showed no characteristic of –OCH3 peak from genipin at 1444 cm-1 which resulted by new covalent bonding occurred between chitosan and genipin. Cross-linking also had increased the oxygen barrier and reduced the water vapor rate through the film. Chitosan film sample with addition of 1 wt% genipin achieved the highest tensile stress average at 49.46 MPa compared to other samples while percent of elongation at break reduced with the increasing of genipin concentration loaded

A study was conducted with the objective of gathering the information through flexural (three-point bending) testing. This research presents the testing results concerning the mechanical properties, modulus of elasticity (MOE) and modulus of rupture (MOR) of natural fiber reinforced composite. Resin were used as a matrix and untreated wood fibres contents 14% by weight as a filler treatment parameters to obtain better compatibility involving wood fibres Sawdust (SW) and Chipwood (CW) and epoxy. The feasibility of processing the composite prepared manually from waste wood and epoxy using open molding was investigated. The tests that have been conducted are in according to ASTM (D790-97) for flexural properties test method. Statistical analysis using ANOVA one way and two way showed that the differences of results obtained from those SW and CW fiber composite samples are significant, which confirm a very firm mechanical performance of the composites through flexural tests. This shows the producing a good quality of SW and CW fibre composite which maybe can use for furniture utilities.

No abstract

In this study, waste wood product obtained from the timber industry originating from various type of wood has been investigated. Research work carried out on the three different sizes of fiber derived from the sawdust (SW) and chip wood (CW). The SW and CW fiber and epoxy resin were blended together respectively using hand tools machine, all specimens of fiber composite were prepared accordance to the ASTM standards. Tensile and morphological properties provide an excellent measure of the degree of reinforcement provided by the fiber to the composite. The tensile modulus increased with the filler size from coast to rough of composites both SW and CW but decreases steadily with the wood–fiber size from rough to soft content. Statistical analysis using one way and two ways analysis of variances (ANOVA) showed that the differences of results obtained from those SW and CW fiber composite samples are significant, which confirm a very firm mechanical performance of the composites through tensile tests. This shows the producing a good quality of SW and CW fibres composite which maybe used for home furniture utilities.