No abstract

Unexpected interface complexities were found resulting from the miscible displacement of saltwater by a miscible shear-thinning solution (xanthan gum) in a radial Hele-Shaw cell, for both convergent and divergent flow. Such complex patterns have not been described before for either Newtonian or non-Newtonian solutions. A more viscous solution was injected into the cell to displace a less viscous solution (divergent flow) then withdrawn at the injection site (convergent flow). A variegated mixing fringe between the solutions developed during the injection phase, against the stabilizing viscous effects, which would tend to promote a stable piston-like displacement. This interface geometry is markedly different from what is seen in displacement experiments performed with glycerol under otherwise similar viscosity contrast and flow conditions. The concentration field heterogeneity resulting from the presence of the fringe, quantified using a spatial autocorrelation measure, is mostly controlled by the applied shear rate, or equivalently, by the ratio of the volumetric flow rate to the flow cell's aperture. It is significantly correlated to the radial width of the mixing zone. In addition to producing a large volume of blended solution during the injection phase, the mixing fringe impacted the development of viscous fingers (VFs) during the withdrawal phase. Such VFs are expected due to the viscosity ratio, but the initial roughness of the interface from which they develop, and, hence, their later dynamics, are controlled by the geometry of the mixing fringe at the end of the injection. We characterize the dynamics as a function of the imposed flow rate and cell thickness. The observed complexities of miscible displacement involving shear-thinning solutions have implications for subsurface engineering applications such as oil recovery and groundwater remediation.

No abstract

Neck and back pathologies cause considerable pain and suffering, and treatment costs tens of billions per year. A common source of problems is degeneration and herniation of the gel-like nucleus pulposus (NP) component of the intervertebral disc, and NP repair/replacement has been a long-term health care goal. We have investigated a novel class of hydrogel/foam composites to identify biocompatible materials with similar viscoelastic characteristics to the native tissue. Low acyl gellan gum (G) and agarose (A) in varying weight percentages were infused into Sugi® cellulose sponge material (F) to produce three candidate materials in addition to those samples without foam. Dynamic oscillatory shear tests and dynamic oscillatory axial compression test tests were conducted on the materials at frequencies between (f = 0.1-10 Hz) to measure elastic (storage) and viscous (loss) moduli in shear and compression conditions. The results show that hydrogel/foam composites show greater viscoelastic properties than hydrogel alone. Various materials of hydrogel and hydrogel/foam composite closely match the viscoelastic properties of native NP tissue.

No abstract