Radiogenic isotopes of Sr and Nd provide crucial information on chemical and physical erosion processes, therefore used as tracers for fingerprinting the sources of fluvial sediments. Moreover, elemental geochemistry, 87Sr/86Sr and 143Nd/144Nd signatures in silicate fractions of sediments primarily reflect intricate controls of characteristics and provenance of sediment. A suite of sediment samples collected from two rivers of India, Narmada (large) and Netravati (small) were analyzed for elemental concentrations, 87Sr/86Sr and 143Nd/144Nd in silicate as well as acid‐leachable fractions. 87Sr/86Sr in acid‐leachable sediment fractions from both the rivers (0.7094 ± 0.0002 for Narmada and 0.7158 ± 0.003 for Netravati) showed more radiogenic 87Sr/86Sr in Netravati compared to Narmada indicating influence of source rocks in their watersheds. Weak correlation of sedimentary 87Sr/86Sr and 143Nd/144Nd with Al and Chemical Index of Alteration (CIA) in silicate fraction indicates that isotopic compositions are primarily controlled by their sources and not by chemical weathering in both the rivers. Provenance of sediments in Narmada is dominated by their supply from Deccan deposits with secondary supply from mid‐late Proterozoic Vindhyan along with Mesoproterozoic to Mesoarchean
TDMNd ages. Sediments from Netravati reflected signatures of peninsular gneisses dominant with gneisses schists and granodiorite along with Paleoarchean
TDMNd ages. Based on variability of 87Sr/86Sr and 143Nd/144Nd, present study highlight that sediment supplies from tributaries to the mainstream in Narmada is inadequate as compared to that in Netravati. 87Sr/86Sr and 143Nd/144Nd signatures in Narmada and Netravati are comparable with Global Rivers.
The stable isotopes of δO, δH, and Sr/Sr and dissolved major ions were used to assess spatial and seasonal water chemistry variability, chemical weathering, and hydrological cycle in the Pangani River Basin (PRB), Tanzania. Water in PRB was NaHCO type dominated by carbonate weathering with moderate total dissolved solids. Major ions varied greatly, increasing from upstream to downstream. In some stations, content of fluoride and sodium was higher than the recommended drinking water standards. Natural and anthropogenic factors contributed to the lowering rate of chemical weathering; the rate was lower than most of tropical rivers. The rate of weathering was higher in Precambrian than volcanic rocks. Sr/Sr was lower than global average whereas concentration of strontium was higher than global average with mean annual flux of 0.13 × 10 mol year. Evaporation and altitude effects have caused enrichment of δO and δH in dry season and downstream of the river. Higher d-excess value than global average suggests that most of the stations were supplied by recycled moisture. Rainfall and groundwater were the major sources of surface flowing water in PRB; nevertheless, glacier from Mt. Kilimanjaro has insignificant contribution to the surface water. We recommend measures to be taken to reduce the level of fluoride and sodium before domestic use.
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