A Michelson interferometer with step-and-integrate mirror motion is described for use in Fourier transform photoacoustic spectrometry (FTPAS) at visible wavelengths. An overview of mechanical and software construction is supplied and the advantages of FTPAS are illustrated with a spectrum of powdered erbium oxide at visible wavelengths. The relative merits of step-and-integrate and rapid scan mirror motion for FTPAS are considered.
Fourier transform infrared photoacoustic (FT-IR-PA) spectroscopy has been used to obtain the first published infrared spectrum of a heavily n-doped polyacetylene. Comparisons are made with the FT-IR-PA spectrum of undoped polyacetylene. All the infrared peaks in the FT-IR-PA spectrum of undoped polyacetylene agree in wavelength to ±10 cm−1 with transmission infrared peaks previously assigned by Shirakawa and Ikeda. Spectral shifts and intensity differences between the n-doped and undoped polyacetylene are similar to changes noted previously in the infrared spectra of p-doped polyacetylenes.
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