No abstract

No abstract

Abstract. When hydrogen, nitrogen and CO are exposed to amorphous iron silicate surfaces at temperatures between 500-900 K a carbonaceous coating forms via Fischer-Tropsch type reactions. Under normal circumstances such a coating would impede or stop further reaction. However, we find that this coating is a better catalyst than the amorphous iron silicates that initiate these reactions. Formation of a self-perpetuating catalytic coating on grain surfaces could explain the rich deposits of macromolecular carbon found in primitive meteorites and would imply that protostellar nebulae should be rich in organic material.

Blends of polypropylene and polyamide‐6,6 have compatibilized with polypropylene that was carboxylated through a reactive extrusion process with an asymmetric functional peroxide. The compatibilized blends demonstrated a finely dispersed minor phase as shown by SEM. Because of the enhanced dispersion, additions of the carboxylated polypropylene to the blends resulted in a change in the crystallization nucleation mechanism of the PA‐6,6 minor phase from heterogeneous to homogeneous in nature. A linear increase in the impact strength and significant enhancement in the tensile properties of the blends was observed with incorporations of the compatibilizer up to 30% of the matrix phase. In addition, the compatibilizing efficiency of the carboxylated polypropylene was compared to the of maleic anhydride functionalized polypropylene. When compared on an equivalent basis (total concentration of carboxylate or anhydride functionality added to the blend), the carboxylated polypropylene demonstrated a slightly better compatibiliziling efficiency than that of the anhydride functionalized polypropylene. The higher compatibilizing efficiency of the carboxylated polypropylene was attributed to a higher grafting efficiency of the carboxylation procedure as compared to the anhydride functionalization procedure.