The CdS quantum dots sensitized TiO2 nanotubes were prepared by sequential chemical bath deposition (S-CBD) method and characterized by FE-SEM and UV-vis spectroscopy. And they were used to degrade the dimethyl phthalate (DMP) in aqueous under sunlight irradiation. The results show that these photo-catalysts have the highest performance, while the initial concentration of dimethyl phthalate in aqueous solution is 10 mg / L, the degradation rates reaches above 80% in the optimum condition which is the CdS deposited 20 cycles, catalyst dosage ~3cm2, and the sunlight irradiating 180 minutes.
An aryl benzyl ester dendritic axially substituted silicon (IV) phthalocyanine, a di-{3,5-di-(4-methoxycarbonyl group benzyloxy) benzyloxy) benzyloxy} axially substituted silicon (IV) phthalocyanine (DSiPc) was synthesized. Its structure was characterized by elemental analysis, 1H NMR, IR and ESI-MS. The photophysical property of DSiPc was studied by steady and time-resolved spectroscopic methods. The steric hindrance of dendritic structure can reduced the aggregation efficiently. The photoinduced intermolecular electron transfer between this novel macromolecule and benzoquinone was studied. The results showed that the fluorescence emission of this dendritic phthalocyanine could be quenched by BQ. Therefore, this novel dendritic phthalocyanine was an effective new electron donor and transmission complex could be used as a potential artificial photosynthesis system.
The compound WO3/TiO2 nanostructures were prepared by the template technique and characterized by FE-SEM and UV-vis DRS. And they were used to degrade the dimethyl phthalate (DMP) under visible light irradiation. The effects of the initial concentration of DMP and dissolved oxygen (DO) were investigated. The results show that degradation rates reaches 59% in the optimum condition which is the catalyst dosage ~3cm2, the DO is 19.2 mg/ L, xenon lamp irradiating 300 minutes and the initial concentration of dimethyl phthalate in aqueous solution is 10 mg / L.
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