Crystal Structure and Spectroscopic Studies of Bis (morpholine dithiocarbamate) Nickel(II) Complex, Ni(C4H8ONCS2)2

Pan, Su Juan; Wang, Ying

doi:10.1002/cjoc.20010190909

Cited by 5 publications

(1 citation statement)

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“…The bond lengths of 2.3019(7) Å for Cu1-S1 and 2.3119(8) Å for Cu1-S2 are typical bond lengths of bis(dithiocarbamato)Cu(II) compounds in a square planar geometry [42]. The bond lengths and angles of the compound are similar to those of the reported Ni(II) morpholine dithiocarbamate complex [43]. The crystal packing for the Cu(II) complex is sustained in the unit cell by inter and intramolecular C-H•••S (Figure 2), in addition to van der Waals forces.…”

Section: Molecular Structures Of the Cu(ii) And Zn(ii) Morpholinyldithiocarbamate Complexessupporting

confidence: 78%

Synthesis, Crystal Structures and Anticancer Studies of Morpholinyldithiocarbamato Cu(II) and Zn(II) Complexes

et al. 2020

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Cu(II) and Zn(II) morpholinyldithiocarbamato complexes, formulated as [Cu(MphDTC)2] and [Zn(μ-MphDTC)2(MphDTC)2], where MphDTC is morpholinyldithiocarbamate were synthesized and characterized by elemental analysis, spectroscopic techniques and single-crystal X-ray crystallography. The molecular structure of the Cu(II) complex revealed a mononuclear compound in which the Cu(II) ion was bonded to two morpholinyl dithiocarbamate ligands to form a four-coordinate distorted square planar geometry. The molecular structure of the Zn(II) complex was revealed to be dinuclear, and each metal ion was bonded to two morpholinyl dithiocarbamate bidentate anions, one acting as chelating ligand, the other as a bridge between the two Zn(II) ions. The anticancer activity of the morpholinyldithiocarbamate ligand, Cu(II) and Zn(II) complexes were evaluated against renal (TK10), melanoma (UACC62) and breast (MCF7) cancer cells by a Sulforhodamine B (SRB) assay. Morpholinyldithiocarbamate was more active than the standard drug parthenolide against renal and breast cancer cell lines, and [Zn(μ-MphDTC)2(MphDTC)2] was the most active complex against breast cancer. The copper(II) complex had a comparable activity with the standard against renal and breast cancer cell lines but showed an enhanced potency against melanoma when compared to parthenolide.

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Section: Molecular Structures Of the Cu(ii) And Zn(ii) Morpholinyldithiocarbamate Complexessupporting

confidence: 78%

Synthesis, Crystal Structures and Anticancer Studies of Morpholinyldithiocarbamato Cu(II) and Zn(II) Complexes

et al. 2020

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Synthesis, characterization and anticancer studies of bis(1-phenylpiperazine dithiocarbamato) Cu(II), Zn(II) and Pt(II) complexes: Crystal structures of 1-phenylpiperazine dithiocarbamato-S,S′ zinc(II) and Pt(II)

Andrew

Ajibade

2018

Journal of Molecular Structure

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Syntheses, characterization, and antimicrobial properties of nickel(II) dithiocarbamate complexes containing NiS₄ and NiS₂PN moieties

Onwudiwe

Ekennia

Hosten

2016

Journal of Coordination Chemistry

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Crystal Structure and Spectroscopic Studies of Bis (morpholine dithiocarbamate) Nickel(II) Complex, Ni(C₄H₈ONCS₂)₂

Cited by 5 publications

References 6 publications

Synthesis, Crystal Structures and Anticancer Studies of Morpholinyldithiocarbamato Cu(II) and Zn(II) Complexes

Synthesis, Crystal Structures and Anticancer Studies of Morpholinyldithiocarbamato Cu(II) and Zn(II) Complexes

Synthesis, characterization and anticancer studies of bis(1-phenylpiperazine dithiocarbamato) Cu(II), Zn(II) and Pt(II) complexes: Crystal structures of 1-phenylpiperazine dithiocarbamato-S,S′ zinc(II) and Pt(II)

Syntheses, characterization, and antimicrobial properties of nickel(II) dithiocarbamate complexes containing NiS₄ and NiS₂PN moieties

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Crystal Structure and Spectroscopic Studies of Bis (morpholine dithiocarbamate) Nickel(II) Complex, Ni(C4H8ONCS2)2

Cited by 5 publications

References 6 publications

Synthesis, Crystal Structures and Anticancer Studies of Morpholinyldithiocarbamato Cu(II) and Zn(II) Complexes

Synthesis, Crystal Structures and Anticancer Studies of Morpholinyldithiocarbamato Cu(II) and Zn(II) Complexes

Synthesis, characterization and anticancer studies of bis(1-phenylpiperazine dithiocarbamato) Cu(II), Zn(II) and Pt(II) complexes: Crystal structures of 1-phenylpiperazine dithiocarbamato-S,S′ zinc(II) and Pt(II)

Syntheses, characterization, and antimicrobial properties of nickel(II) dithiocarbamate complexes containing NiS4 and NiS2PN moieties

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Crystal Structure and Spectroscopic Studies of Bis (morpholine dithiocarbamate) Nickel(II) Complex, Ni(C₄H₈ONCS₂)₂

Syntheses, characterization, and antimicrobial properties of nickel(II) dithiocarbamate complexes containing NiS₄ and NiS₂PN moieties