Manganese oxide nanoparticles (MONPs) are capable of time‐dependent magnetic resonance imaging contrast switching as well as releasing a surface‐bound drug. MONPs give T2/T2* contrast, but dissolve and release T1‐active Mn2+ and L‐3,4‐dihydroxyphenylalanine. Complementary images are acquired with a single contrast agent, and applications toward Parkinson's disease are suggested.
An important aspect of efficient
treatment of produced water is
to promote the coalescence of dispersed oil drops. Therefore, a fundamental
understanding of the relations between interfacial and physicochemical
properties of crude oils and the coalescence process is essential,
and elucidating these relationships was the aim of this investigation.
Nine crude oils and fractions of two crude oils, where acids, bases,
and asphaltenes were selectively extracted, were included in the studies.
The dynamic interfacial tension and interfacial rheology of the oils
were followed in synthetic produced water. The binary coalescence
of oil drops was followed by a micropipette setup, and characteristic
times for three phenomena occurring during the coalescence process
were identified: the time of film thinning, the time for rupture of
the thin film, and the apparent time of merger of the two drops. Decreasing
the density of the crude oils and increasing the strength of the interfacial
layer were determined to influence the coalescence process most significantly,
by slowing it down. The elasticity and strength of the interfacial
layers were primarily associated with the presence of asphaltenes
at the interface. The strength of the interfacial layer decreased
as the amount of aromatics and acidic components in the crude oil
increased. In both cases, this was attributed to improved stability
of the asphaltenes in the bulk of the crude oil.
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