Currently, the use of secondary agricultural raw material is a topical issue. There are various applications of agricultural crop residues possible, but they are finance- and energy-consuming. Burning crop residues is very harmful for the environment. One of the ways to solve the problem is the production of solid biofuel that can be used to heat buildings. The authors suggest producing solid biofuel in the form of small-sized fuel rolls / pellets (SFR), which are made of oleaginous flax residues. As a result of the conducted experimental investigations, the authors have proved the efficiency and the environmental safety of SFR consumption. The new fuel can be recommended if the requirement of efficient and ecologically safe combustion is met. Thus, the influence of small-sized fuel rolls’ properties on the process of their combustion as well as quantitative and qualitative analysis of the combustion gases from burning solid fuel made of oleaginous flax residues have been investigated. The paper presents the results proving that SFR combustion is the most efficient on condition of providing reduced moisture (10-12%) and reasonable density (80 kg/m3) in the process of pellet production. In addition, it has been determined that there is a significant reduction of harmful CO emissions and normalization of СО2 concentration. The application of the suggested solid biofuel can make it possible to solve the problem of using oleaginous flax residues and provide cheap fuel for household purposes.
Harvesting of oleaginous flax seeds creates a biomass of stem residues that needs to be processed or utilized. Many methods of processing this biomass into various products (fiber, fuel, composites, etc.) have been offered. The first step in processing oleaginous flax residue is spinning it into rolls. However, oleaginous flax stems have highly elasticity properties and quick recovering abilities which make residue processing difficult. This paper suggests methods of decreasing the elasticity properties of oleaginous flax residue by destroying the higher layer of stem – decortication. Elasticity properties are influenced by layer thickness, humidity, and the amount of flax breakage as it passes through the roller pairs of a roller machine (decorticator). An increase in humidity and in the number of passes through the decorticator makes elasticity properties decrease. It allows making rolls that will keep their shape for a long period without any additional influences. In the future, these rolls can be used as a fuel or for a longer processing. The research results show a correlation with the rational number of machine roller pairs which can be used to develop new engineering designs for oleaginous flax harvesting.
The procedure for the identification of white jewelry alloys based on precious metals, in particular, silver, platinum and platinum group metals with different contents of alloying components, by testing on an assay stone and by the method of X-ray fluorescence analysis has been considered. The methodology for assessing the compliance of silver and platinum fineness in white jewelry alloys of different component composition with the requirements of regulatory documents and the procedure for their identification has been improved. It has been established that the silver fineness in precious alloys of the AgCu, AgZnCu system, determined using the potassium dichromate reagent on the test stone, depends on the manifestation of the contrast of the qualitative reaction from the standard sample (assay needle). It has been proven that for testing silver alloys containing palladium, the "Acid reagent for gold 750" is effective, which works to determine the qualitative and approximate content of silver in alloys. It was determined that the reagent "Ferrous-cyanide potassium" is very sensitive to changes in the alloy composition of silver alloys and makes it possible to establish the silver content with an accuracy of 5 %. The presence in silver alloys of such impurities as zinc, cadmium, nickel, gold, palladium and others increases the error in determining the fineness of silver and forms a different color and shade. It has been proven that testing of silver alloys on an assay stone with silver nitrate is effective only for the СрМ system. The presence of zinc in 925 sterling silver alloys visually increases the color intensity of the sediment, which indicates a higher overestimated fineness. It has been found that the identification of the content of precious alloys based on platinum for the presence of ligature components is carried out with a potassium iodide reagent at t=120 °C by the color and shade of the sediment. The procedure for using potassium iodide during testing of precious platinum-based alloys has been optimized
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