CdTe thin film (TF) solar cells are most promising photovoltaic (PV) technology in commercial platform. Back contacts and interface defects related opto-electrical losses are still vital to limit its further technological benefit. TF PV cells shallow recombination and parasitic loss lessening purpose carrier selective back contact with band matching window layers are essential. Beside that back and front contact thickness choice is vital for field associated selective carrier collection and generous optical transmission into the active junction of the cell. It can make variation of cell efficiency. Window and front contact layers band edge variation and back contact thickness effect is analyzed by SCAPS-1D simulation software. ZnO and SnO2 front contact for CdS and CdSe window layers effect are numerically studied for 1 μm CdTe thin film PV cell. Significance of materials for front contact and its thickness effect on current density while ZnTe back surface field contact thickness effect on open circuit voltage and efficiency are demonstrated. Finally, ZnO/CdS/CdTe/ZnTe cell of 0.925 V open circuit voltage and 19.06% efficiency has been achieved for 90 nm of ZnTe with Molybdenum (Mo) back contact.
This study investigates the structural and optical characteristics of Silicon Germanium (SiGe) thin films with varying compositions and annealing temperatures for potential use in electronic and optoelectronic devices. Si0.8Ge0.2 and Si0.9Ge0.1 films were deposited onto a high-temperature quartz substrate and annealed at 600 °C, 700 °C, and 800 °C before being evaluated using an X-Ray Diffractometer (XRD), Atomic Force Microscopy (AFM), and a UV-Vis Spectrometer for structural and optical properties. The results show that increasing the annealing temperature results in an increase in crystalline size for both compositions. The transmittance for Si0.8Ge0.2 decreases slightly with increasing temperature, while Si0.9Ge0.1 remains constant. The optical band gap for Si0.9Ge0.1 thin film is 5.43 eV at 800 °C, while Si0.8Ge0.2 thin film is 5.6 eV at the same annealing temperature. XRD data and surface analysis reveal significant differences between the band edges of SiGe nano-structure materials and bulk crystals. However, the possibility of a SiGe nano-crystal large band gap requires further investigation based on our study and related research works.
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