This study is focused on the mineral assemblages developed during hydrothermal alteration in the host rocks of the Chelopech deposit and aims to reveal some characteristics of ore-forming fluids. Three well-distinguished and simultaneously formed hydrothermal alteration zones, characterized by specific mineral associations, occur in the area: advanced argillic, sericitic and propylitic. The presence of silica residue localities in the advanced argillic zone marks the major channels of hydrothermal fluids and indicates participation of extremely acid fluids. The existence of alunite and zunyite in the alteration indicates development of acid-sulphate hydrothermal environment, with presence of F in the fluid, which is considered to be an important feature of ore-bearing high-sulphidation epithermal systems. Dickite in association with alunite in the upper levels of the deposit suggests temperature of formation 200–250 °C. The highest temperature in depth is limited up to 375 °C, considering the occurrence of zunyite, pyrophyllite and dickite.
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