While the optical properties of thin metal films are well understood in the visible and near-infrared range, little has been done in the mid-and far-infrared region. Here we investigate ultra-thin gold films prepared on Si(111)(7 × 7) in UHV by measuring in the frequency range between 500 cm −1 and 7000 cm −1 and for temperatures between 300 K and 5 K. The nominal thickness of the gold layers ranges between one monolayer and 9 nm. The frequency and temperature dependences of the thicker films can be well described by the Drude model of a metal, when taking into account classical size effects due to surface scattering. The films below the percolation threshold exhibit a non-metallic behavior: the reflection increases with frequency and decreases with temperature. The frequency dependence can partly be described by a generalized Drude model. The temperature dependence does not follow a simple activation process. For monolayers we observe a transition between surface states around 1100 cm −1 .

The optical properties of ultrathin Au films on silicon have been studied in the infrared over a wide frequency range from 200 to 10,000 cm(-1). Thick films show a Drude behavior; i.e., with increasing frequency the transmission increases; for films below the percolation threshold at about 5 nm a negative slope for the frequency-dependent transmission is observed. When the thickness is further reduced, between 1 and 3 nm an anomaly occurs: the relative transmission reaches maximum values above 100% compared with the bare substrate, indicating an antireflection coating of nanometer thickness for light of 5 microm wavelength. This anomaly can be explained in the framework of effective-medium theories.

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