Wavelength tuning of whispering gallery lasing modes has been observed from Rhodamine-B-doped polymer fibers under tensile strain. Good quality whispering gallery lasing modes are produced from both solid and hollow fibers by transverse optical pumping. The lasing modes are shifted linearly toward the shorter wavelength side when the fiber is elongated in the axial direction. Compared with solid fiber, the lasing modes of hollow fiber can be tuned over the entire gain spectrum with a tuning range of ∼5 nm. It is found that the tuning of the lasing modes of hollow fiber is reversible.
We report the structural engineering of ZnO nanostructures by a consistent solution method using distinct solvents such as ethylene glycol, 1-butanol, acetic acid and water. The growth kinetics are found to depend strongly on the physicochemical properties of the solvent and zeta potential of the colloidal solution. Furthermore, the resulting nanostructures as a photoanode material, displayed a prominent structure dependent property in determining the efficiency of dye-sensitized solar cells (DSSCs). The fabricated solar cell with ZnO nanostructures based photoanode exhibited improved conversion efficiency. Moreover, the nanoflower based DSSCs showed a higher conversion efficiency of 4.1% compared to the other structures. The excellent performance of ZnO nanoflower is attributed to its better light-harvesting ability and increased resistance to charge-recombination. Therefore ZnO nanostructures can be a promising alternative for TiO2 in DSSCs. These findings provide new insight into the simple, low cost and consistent synthetic strategies for ZnO nanostructures and its outstanding performance as a photoanode material in DSSCs.
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