Several methods for the analysis of remotely sensed reflectance data are compared, including empirical methods and scattering theories, both of which are important for solving remote sensing problems. The concept of the photon mean optical path length and the implications for use in modeling reflectance spectra are presented. It is shown that the mean optical path length in a particulate surface is in rough inverse proportion to the square root of the absorption coefficient. Thus, the stronger absorber a material is, the less photons will penetrate into the surface. The concept of apparent absorbance (‐In reflectance) is presented, and it is shown that absorption bands, which are Gaussian in shape when plotted as absorption coefficient (true absorbance) versus photon energy, are also Gaussians in apparent absorbance. However, the Gaussians in apparent absorbance have a smaller intensity and a width which is a factor of √2 larger. An apparent continuum in a reflectance spectrum is modeled as a mathematical function used to isolate a particular absorption feature for analysis. It is shown that a continuum should be removed by dividing it into the reflectance spectrum or subtracting it from the apparent absorbance and that the fitting of Gaussians to absorption features should be done using apparent absorbance versus photon energy. Kubelka‐Munk theory is only valid for materials with small total absorption and for bihemispherical reflectance, which are rarely encountered in geologic remote sensing. It is shown that the recently advocated bidirectional reflectance theories have the potential for use in deriving mineral abundance from a reflectance spectrum.
Abstract. The Thermal Emission Spectrometer (TES) investigation on Mars GlobalThe TES data are calibrated to a 1-o-precision of 2.5 -6 X 10 -8 W cm -2 sr-1/cm -•, 1.6 x 10 -6 W cm -2 sr -•, and -0.5 K in the spectrometer, visible/near-IR bolometer, and IR bolometer, respectively_. These instrument subsections are calibrated to an absolute accuracy of-4 x 10 -8 W cm -2 sr-•/cm -• (0.5 K at 280 K), 1-2%, and -1-2 K, respectively. Global mapping of surface mineralogy at a spatial resolution of 3 km has shown the following: (1) The mineralogic composition of dark regions varies from basaltic, primarily plagioclase feldspar and clinopyroxene, in the ancient, southern highlands to andesitic, dominated by plagioclase feldspar and volcanic glass, in the younger northern plains. (2) Aqueous mineralization has produced gray, crystalline hematite in limited regions under ambient or hydrothermal conditions; these deposits are interpreted to be in-place sedimentary rock formations and indicate that liquid water was stable near the surface for a long period of time. (3) There is no evidence for large-scale (tens of kilometers) occurrences of moderate-grained (>50-•m) carbonates exposed at the surface at a detection limit of -10%. (4) Unweathered volcanic minerals dominate the spectral properties of dark regions, and weathering products, such as clays, have not been observed anywhere above a detection limit of -10%; this lack of evidence for chemical weathering indicates a geologic history dominated by a cold, dry climate in which mechanical, rather than chemical, weathering was the significant form of erosion and sediment production. (5) There is no conclusive evidence for sulfate minerals at a detection limit of -15%. The polar region has been studied with the following major conclusions: (1) Condensed CO2 has three distinct end-members, from fine-grained crystals to slab ice. (2) The growth and retreat of the polar caps observed by MGS is virtually the same as observed by Viking 12 Martian years ago. (3) Unique regions have been identified that appear to differ primarily in the grain size of CO2; one south polar region appears to remain as black slab CO2 ice throughout its sublimation. (4) Regional atmospheric dust is common in localized and regional dust storms around the margin and interior of the southern cap. Analysis of the thermophysical properties of the surface shows that (1) the spatial pattern of albedo has changed since Viking observations, (2) a unique cluster of surface materials with intermediate inertia and albedo occurs that is distinct from the previously identified lowinertia/bright and high-inertia/dark surfaces, and (3) localized patches of high-inertia material have been found in topographic lows and may have been formed by a unique set of aeolian, fluvial, or erosional processes or may be exposed bedrock.• •Raytheon Santa Barbara Remote Sensing, Goleta, California. IntroductionThe Thermal Emission Spectrometer (TES) experiment is designed to address a wide range of science objectives, including the de...
Geochemical models for Mars predict carbonate formation during aqueous alteration. Carbonate-bearing rocks had not previously been detected on Mars' surface, but Mars Reconnaissance Orbiter mapping reveals a regional rock layer with near-infrared spectral characteristics that are consistent with the presence of magnesium carbonate in the Nili Fossae region. The carbonate is closely associated with both phyllosilicate-bearing and olivine-rich rock units and probably formed during the Noachian or early Hesperian era from the alteration of olivine by either hydrothermal fluids or near-surface water. The presence of carbonate as well as accompanying clays suggests that waters were neutral to alkaline at the time of its formation and that acidic weathering, proposed to be characteristic of Hesperian Mars, did not destroy these carbonates and thus did not dominate all aqueous environments.
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