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The importance of temporal variability in relationships between phosphorus (P) concentration (C p ) and discharge (Q) is linked to a simple means of classifying the circumstances of C p Q relationships in terms of functional types of response. New experimental data at the upstream interface of grassland soil and catchment systems at a range of scales (lysimeters to headwaters) in England and Australia are used to demonstrate the potential of such an approach. Three types of event are defined as Types 13, depending on whether the relative change in Q exceeds the relative change in C p (Type 1), whether C p and Q are positively inter-related (Type 2) and whether C p varies yet Q is unchanged (Type 3). The classification helps to characterise circumstances that can be explained mechanistically in relation to (i) the scale of the study (with a tendency towards Type 1 in small scale lysimeters), (ii) the form of P with a tendency for Type 1 for soluble (i.e., <0.45 mm P forms) and (iii) the sources of P with Type 3 dominant where P availability overrides transport controls. This simple framework provides a basis for development of a more complex and quantitative classification of C p Q relationships that can be developed further to contribute to future models of P transfer and delivery from slope to stream. Studies that evaluate the temporal dynamics of the transfer of P are currently grossly under-represented in comparison with models based on static/spatial factors.

Soil erosion, in the form of transported suspended sediment in overland flow, is often associated with high rates of particulate phosphorus (PP) (total P&gt;0.45 μm) transfer from land to watercourses. Particulate P may provide a long-term source of P for aquatic biota. Twenty-two sites for winter overland flow monitoring were selected in south-west England within fields ranging from 0.2–3.8 ha on conventionally-managed arable land. Fields were situated on highly porous, light textured soils, lacking impermeable horizons and often overlying major aquifers. Long arable use and modern cultivation methods result in these soils capping under rain impact. Overland flow was observed when rainfall intensity approached the modest rate of 0.8 mm hr−1 on land at or near to field capacity. Low intensity rainfall (&lt;2 mm hr−1) produced mean suspended sediment losses of 14 kg ha−1 hr−1, with associated PP transfer rates of 16 g ha−1 hr−1. In high intensity rainfall (&gt;9 mm hr−1) mean PP losses of 319 g ha−1 hr−1 leaving the field were observed. As might be expected, there was a good relationship between PP and suspended sediment transfer in overland flow leaving the sites. The capacity of light soils to cap when in arable use, combined with heavy or prolonged rainfall, resulted in substantial discharges, soil erosion and associated PP transfer. Storms with heavy rain, typically of only a few hours duration, were characterised by considerable losses of PP. Such events, with return periods of once or twice a winter, may account for a significant proportion of total annual P transfer from agricultural soils under arable crops. However, contributions from less intense rain with much longer duration (around 100 hours per winter in many arable districts of the UK) are also demonstrated here.

Following recommendations by the 19th Royal Commission on Environmental Pollution, the area, causes and rates of upland soil erosion in England and Wales were investigated between 1997 and 1999. This paper describes the methods and results of the field survey of 1999 in which the extent of eroded ground was determined. 2. The area of degraded soil and the volume of eroded material were both determined from the dimensions of individual erosion features at 399 field sites located on an orthogonal grid across the uplands. Using measurements of individual erosion features, degraded soil extent in upland England and Wales was estimated at almost 25 000 ha, 2·46 per cent of the total upland area surveyed. Half this eroded area was revegetated and no longer subject to continued accelerated soil loss in 1999. The total volume of eroded material was estimated at 0·284 km3. Although deposition of eroded material occurred within 20 per cent of eroded field sites, the total volume of redeposited material was less than 1 per cent of the total volume of eroded soil. 3. Erosion was more extensive on peat soils than on dry, wet mineral or wet peaty mineral soils. In addition, the higher incidence of erosion at high altitudes and on low slopes reinforced the relationship between erosion and areas of peat formation. Copyright © 2002 John Wiley & Sons, Ltd.

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