The new macrocyclic ligand 5,5'-ethane bis-(10,14-dihydroxo 12-thio,1,5,9-triazacyclotetradeca 1,9-diene) has been prepared and characterised. Its transition metal complexes have been prepared and characterised by Melting point, elemental analyses, molar conductence, electronic and IR spectral studies.Based on these studies, probable structures have been proposed for these complexes

A fully conjugated ligand 4,42 -bis (1,10-phenanthroline-[5,6-d]imidazole-2-yl)-biphenyl based on 1,10-phenanthroline and biphenyl groups was firstly synthesized. The corresponding polymeric macrocyclic complexes with Ti(III) and V(III) were synthesized and characterized by FT-IR, elemental Analysis, conductivity measurement, UV-Vis and luminescence spectra at room temperature revealed that both the polymeric complexes emit blue luminescence at 453 and 452 nm (λ em, max ) in DMSO solution and blue/green luminescence at 527 and 536 nm (λ em, max ) in solid state respectively, and the maximum wavelengths of the polymeric complexes are red shifted, compared with the ligand. On the bases of study performed and discussed an octahedral environment seems to exist around metal ion in the complex

ABSTRACTβ-diketone with oligo (ethylene oxide) group and its transition metal complexes were synthesized and characterized by 'HNMR, IR, Electronic spectra, m.p., elemental analyses and magnetic studies. Based on these studies probable structures have been proposed for these metal chelates. .

No abstract