Abstract-The Zak≥odzie meteorite was found in September 1998, about 40 km west of ZamoúÊ, in southeast Poland. Macroscopic and microscopic observations (in transmitted and reflected light), microprobe analyses, cathodoluminescence images, and X-ray diffraction data show that the meteorite is composed of clino-and orthoenstatite, two generations of feldspars, relict olivine (forsterite), a polymorph of SiO 2 (apparently cristobalite), and opaque minerals: Fe-Ni alloy (kamacite and taenite), troilite, schreibersite, graphite, and sulfide (Mg, Mn, Fe)S, which is probably keilite. The texture is fine-to inequigranular of cumulate type, locally intergranular. The MgS-FeS thermometer indicates that the sulfides crystallized at ∼580-600 ºC. Thus, the Zak≥odzie meteorite formed by the nearly complete melting of an enstatite chondrite protolith, probably at ∼4.4 Ga; the process was likely caused by the decay of the 26 Al nuclide in the planetesimal interior. The second stage of its evolution, which could have happened at ∼2.1 Ga, involved partial re-melting of most fusible components, probably due to collision with another body. The structure, composition, and origin of the meteorite and its relation to the parent rock indicate that Zak≥odzie may represent a primitive enstatite achondrite.
A total of 2143 dissolved radon-222 and radium-226 activity concentrations measured together in water samples was compiled from the literature. To date, the use of such a large database is the first attempt to establish a relationship for the 226Ra–222Rn couple. Over the whole dataset, radon and radium concentrations range over more than nine and six orders of magnitude, respectively. Geometric means yield 9.82±0.73 Bq l−1 for radon and 54.6±2.7 mBq l−1 for radium. Only a few waters are in 226Ra–222Rn radioactive equilibrium, with most of them being far from equilibrium; the geometric mean of the radium concentration in water/radon concentration in water (CRa/CRn) ratio is estimated to be 0.0056±0.0004. Significant differences in radon and radium concentrations are observed between groundwaters and surface waters, on the one hand, and between hot springs and cold springs, on the other. Within water types, typical ranges of radon and radium concentrations can be associated with subgroups of waters. While the radium concentration characterizes the geochemistry of the groundwater–rock interaction, the radon concentration, in most cases, is a signal of non-mobile radium embedded in the encasing rocks. Thus, the 226Ra–222Rn couple can be a useful tool for the characterization of water and for the identification of water source rocks, shedding light on the various water–rock interaction processes taking place in the environment.
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