The influence of KOH concentration (8 and 12 M) and curing conditions as temperature (40˚C and 60˚C), time (7 and 28 days) and relative humidity (85% and 95% RH), on compressive strength of metakaolin-based geopolymers (MK-based GP) was evaluated. Derived from the experimental design technique, and using a factorial design 2 K with two replications in the center point, eighteen experiments were conducted. The results reveal that the best performance conditions of geopolymerization to develop a higher compressive strength of 20 MPa are 12 M KOH to 60˚C and 85% RH at 28 curing days. With these conditions, the value of relative humidity of 85%, promotes high strength compact samples, and a maximum of 42 MPa at 90 days. The results of significant, compressive design of GP showed that KOH concentration and curing relative humidity were the most important factors, followed by curing time and temperature. The GP were characterized by XRD, and their evolution on compression strength was followed by SEM.
The present work is a study on alkali activation of Mexican blast furnace slag, using sodium silicate. The aim is to produce an optimal specimen, homogeneous without carbonation, and with small fraction of crystalline phases, similar to CSH, which provide mechanical properties suitable to use in the construction industry. The samples were prepared using sodium silicate activator solutions with modulus (SiO2/Na2O) of 1.25, 1.5, and 1.75. The weight percentage of Na2O in the activator solutions was added at 4, 6 and 8% relative to the slag weight. The prepared samples were stored in sealed molds, at room temperature (20°C), during 7 days. The X-ray diffraction has revealed the presence of an amorphous phase, semi crystalline clinotobermorite phase and signals of calcium carbonate for the samples of 4 and 6 % of Na2O; in contrast with the 8% Na2O, where the latter signals almost disappeared. The specimen selected as optimal was prepared with an activator concentration of 8% of Na2O /Slag, and SiO2/Na2O of 1.25. A specimen under these optimal conditions was prepared with accelerated curing (40°C, humidity, 48 hours), and a compressive strength test was attained, with an average value of 52 MPa at 3 days.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.