Enantioselective Catalysis CXXI [1]: Chiral Phosphane Ligands with Additional Oxygen FunctionalitiesSummary. New optically active phosphane ligands with additional ether and hydroxy functionalities were synthesied and used as sources of enantio-selectivity in the Ni-catalyzed cross coupling reaction of 1-phenylethyl Grignard and vinylbromide and in the Pd-catalyzed allylation of 1,5-dimethylbarbituric acid with allyl acetate.

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