We found that oxidized Cu nanoparticles can catalyze the growth of boron nitride nanotubes from borazine via plasma-assisted chemical vapor deposition. The Raman spectra suggest that the formation of thin-walled nanotubes show a radial breathing mode vibration. The presence of oxygen in the plasma environment was necessary for the growth of the nanotubes, and a part of the nanotubes had a core shell structure with a cupper species inside it. In atomic resolution transmission electron microscope (TEM) images, Cu2O was found at the interface between the Cu-core and turbostratic BN-shell. The growth mechanism seemed different from that of carbon nanotube core-shell structures. Therefore, we pointed out the important role of the dynamic morphological change in the Cu2O-Cu system.
The choice of a catalyst for carbon nanotube (CNT) growth is critical to controlling the morphology and chirality of the final product. Plasma-enhanced chemical vapor deposition (PECVD) can alleviate the requirements of the catalyst, i.e., they must be active for both the decomposition of the source gas and graphitization in the conventional thermal CVD. However, it is still not well understood how the catalytic activity of the graphitization affects the yield and quality of CNTs. In this paper, we systematically investigated the influence of the catalytic activity of graphitization by tuning the composition of Fe 1−x Mn x O (x = 0-1) nanoparticles as catalysts. As the Mn component increased, the number of CNTs decreased because Mn has no catalytic function of the graphitization. The quality of CNTs also affected by the inclusion of the Mn component. Our study may provide useful information to develop a new catalyst for CNT growth in PECVD.
We propose a new optical intersatellite communications system with a phase conjugate mirror (PCM) in formation flying (FF). In conventional optical intersatellite communications, high-accurate target acquisition and tracking are required for both the transmitter and the receiver. In our system with a PCM, when a control beam from the receiver is captured by a PCM in the transmitter, the signal beam from the transmitter introduced back to the receiver as its phaseconjugate replica. Thus, it is not necessary for the transmitter to target the receiver. Another advantage of using a PCM is that we can utilize spatial filtering. Background noise by sunlight with the laser wavelength can also be efficiently suppressed by a spatial phase modulation/demodulation and filtering processes using phase compensation by the PCM, which leads to the improvement of the signal-to-noise ratio (SNR) and hence provides high data transmission rates in the system. In order to efficiently filter out the background noise, a large beam propagation angle is required in spatial filtering. We spatially modulate the background noise by the diffuser and reduce the beam diameter by the expansion/downscale optical system as a method to enlarge the beam propagation angle.In this paper, we show that our system can separate the noise from the signal by using the expansion/downscale optical system even under spatial phase modulation. In the analysis, the SNR is 32.6[dB] at scale=8.0×10 4 , when a spatial phase modulation by the diffuser is θ=1.5×10 -5 [rad].
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