[1] We examine the quality of atmospherically deposited ion and isotope signals in an ice core taken from a periodically melting ice field, Lomonosovfonna in central Spitsbergen, Svalbard. The aim is to determine the degree to which the signals are altered by periodic melting of the ice. We use three diagnostics: (1) the relation between peak values in the ice chemical and isotopic record and ice facies type, (2) the number of apparent annual cycles in these records compared with independently determined number of years represented in the ice core, and (3) a statistical comparison of the isotopic record in the ice core and the isotope records from coastal stations from the same region. We find that during warm summers, as much as 50% of the annual accumulation may melt and percolate into the firn; in a median year this decreases to $25%. As a consequence of percolation, the most mobile acids show up to 50% higher concentrations in bubble-poor ice facies compared with facies that are less affected by melt. Most of the other chemical species are less affected than the strong acids, and the stable water isotopes show little evidence of mobility. Annual or biannual cycles are detected in most parameters, and the water isotope record has a comparable statistical distribution to isotopic records from coastal stations. We conclude that ice cores from sites like Lomonosovfonna contain a useful environmental record, despite melt events and percolation and that most parameters preserve an annual, or in the worst cases, a biannual atmospheric signal.
In 1997 a 121m ice core was retrieved from Lomonosovfonna, the highest ice field in Spitsbergen, Svalbard (1250 m a.s.l.). Radar measurements indicate an ice depth of 126.5 m, and borehole temperature measurements show that the ice is below the melting point. High-resolution sampling of major ions, oxygen isotopes and deuterium has been performed on the core, and the results from the uppermost 36 m suggest that quasi-annual signals are preserved. The 1963 radioactive layer is situated at 18.5^18.95 m, giving a mean annual accumulation of 0.36 m w.e. for the period 1963^96. The upper 36 m of the ice core was dated back to 1920 by counting layers provided by the seasonal variations of the ions in addition to using a constant accumulation rate, with thinning by pure shear according to Nye (1963). The stratigraphy does not seem to have been obliterated by meltwater percolation, in contrast to most previous core sites on Svalbard. The anthropogenic influence on the Svalbard environment is illustrated by increased levels of sulphate, nitrate and acidity. Both nitrate and sulphate levels started to increase in the late 1940s, remained high until the late 1980s and have decreased during the last 15 years. The records of 18 O, MSA (methanesulphonic acid), and melt features along the core agree with the temperature record from Longyearbyen and the sea-ice record from the Barents Sea at a multi-year resolution, suggesting that this ice core reflects local climatic conditions.
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