We report a systematic study on the role of Marangoni convection on the evaporation kinetics of pure water drops, considering the influence of heating regime and surface wettability. The Marangoni flows were induced via heating under constant wall temperature (uniform heating) and constant heat flux (local heating) regimes below the drops. To visualize the thermal patterns/flows emerging within the water drops we employed infrared (IR) thermography and we captured the evolution of the drop profile with a CCD camera to follow the evaporation kinetics of each drop. We observed a strong correlation between the temperature difference within the drop and the evolution of drop shape during different modes of evaporation (i.e. constant radius, angle or stick-slip) resulting in different Marangoni flow patterns. Under uniform heating, stable recirculatory vortices due to Marangoni convection emerged at high temperature which faded at later stages of the evaporation process. On the other hand, in the localized heating case, the constant heat flux resulted in a rapid increase of the temperature difference within the drop capable of sustaining Marangoni flows throughout the evaporation. Surface wettability was found to also play a role in both the emergence of the Marangoni flows and the evaporation kinetics. In particular, recirculatory flows on hydrophobic surfaces were stronger when compared to hydrophilic for both uniform and local heating. To quantify the effect of heating mode and the importance of Marangoni flows, we calculated the evaporative flux for each case and found to it to be much higher in the localized heating case. Evaporative flux depends on both diffusion and natural convection of the vapor phase to the ambient. Hence, we estimated the Grashof number for each case and found a strong relation between natural convection in the vapor phase and heating regime or Marangoni convection in the liquid phase. Subsequently, we demonstrate the limitation of current diffusion-only models describing the evaporation of heated drops. 32 90°, the CCA mode of evaporation is reported and the 33 decrease in weight/volume is observed to be non-linear. 34 Further, the decrease in volume according to a power law 35 is reported for drops evaporating on hydrophobic and su-36 perhydrophobic surfaces [8, 9]. Apart from the extreme 37 modes of evaporation (CCR and CCA), a stick-slip mode 38 of evaporation with repetitive cycles of stick and slip of 39 the contact line is observed for pure fluids [10] and also 40 for colloidal suspensions [11]. The strong influence of 41 substrate wettability [8, 12], shape of the sessile drop 42 [13], ambient conditions [14-16] and substrate proper-43 ties [17, 18] on the evaporation process are extensively 44 reported. 45 For a sessile drop in contact with a solid substrate, 46 the evaporative flux at the liquid-vapor interface is non-47 uniform and depends on the drop shape [19]. The evap-48 orative flux is higher near the contact line for drops with 49 contact angles less than 90°, whereas for d...

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In the present work, the thermal performance of a double glazed single pass solar air heater consisting of a longitudinally finned absorber plate on its top surface and attached to a phase change material (PCM) with its bottom surface is investigated, theoretically. Paraffin wax (Rubitherm RT42) is used as a PCM. The main idea of this solar air heater design is to use it during nocturnal hours or off sunshine hours. A computational heat transfer and fluid dynamics solution using an implicit scheme has been developed and employed to study the effects of the mass flow rate and number of fins on its thermal performance under transient conditions. The maximum outlet air temperature of the finned type solar air heater with latent heat storage is achieved as 40 °C, 37 °C, and 35 °C for mass flow rates of 0.01, 0.015, and 0.02 kg/s, respectively, and it is predicted that the system can be used for 14, 12, and 10 h after sunset at respective mass flow rates. The maximum daily average thermal efficiency is predicted to be 62.4% at a mass flow rate of 0.02 kg/s which is higher than the other designs considered in the present investigation.

Understanding the internal flow in evaporating sessile drops is of paramount importance in a myriad of applications such as ink-jet printing, surface patterning, and medical diagnostics. Marangoni flow driven by a gradient in surface tension is an essential internal flow mechanism, whose characteristics in evaporating water drops remain elusive in the literature. Here, by employing infrared thermography and particle image velocimetry, we show that the manifestation of Marangoni flow as a convective cell at the liquid–vapor interface results in a nonaxisymmetric internal flow field. Eventually, during evaporation, the flow transitions to a buoyancy-dominated regime, where an axisymmetric toroidal flow is observed. This transition marks a reversal in the flow along with an order of magnitude decrease in velocity. We corroborate this experimentally observed transition using previously reported analytical and scaling frameworks. Finally, we present hitherto unreported features correlating the three aspects of evaporating water drops, viz., contact line dynamics, thermal field, and internal flow field, which are generally investigated independently.