Different from fossil diesel, biodiesels can be manufactured from different sources of biomass or animal fat. Each biodiesel manufactured from a certain feedstock consists of different fatty acid methyl esters (FAMEs). Its FAME types and fractions are unique and are solely controlled by the mother feedstock and not the manufacturing process. One key feature that makes biodiesels different from their fossil counterparts is the oxygen contained in biodiesels. The oxygen content, FAME types, and FAME fractions vary in a wide range among biodiesels made from different feedstock and this in turn affects the fuel properties and physical processes, including atomization and evaporation. An extensive analysis has been successfully carried out in this study to examine the role of oxygen content, carbon chain length, and unsaturation degree in different biodiesels and the influence of FAMEs on key fuel properties (heating value, cetane number, viscosity, and surface tension). Furthermore, some useful information related to (i) the morphology and density of fuel fragments derived close to the nozzle exit and (ii) drop evaporation is reported. The atomization characteristics are experimentally observed using a high-speed imaging technique developed earlier, while the evaporation study is theoretically conducted using the well-known D-square model. It shows that the oxygen in the biodiesel is directly linked to the carbon chain length and the number of double bonds in the fuel molecules as well as to the key fuel properties. The viscosity of biodiesels and their constituents has a certain impact on the morphology and population of fuel fragments derived in the breakup zone, while the thermal properties have a significant effect on biodiesel evaporation. The dependence of fuel properties on atomization at the downstream locations of the spray, where the breakup process has completed, is minimal.

Examining the influence of thermal conditions in the engine cylinder at the start of fuel injection on engine combustion characteristics is critically important. This may help to understand physical and chemical processes occurring in engine cycles and this is relevant to both fossil fuels and alternative fuels like biodiesels. In this study, six different biodiesel–diesel blends (B0, B10, B20, B40, B60 and B100 representing 0, 10, 20, 40, 60 and 100% by volume of biodiesel in the diesel–biodiesel mixtures, respectively) have been successfully tested in a cooperative fuel research (CFR) engine operating under a wide range of thermal conditions at the start of fuel injection. This is a standard cetane testing CFR-F5 engine, a special tool for fuel research. In this study, it was further retrofitted to investigate combustion characteristics along with standard cetane measurements for those biodiesel blends. The novel biodiesel has been produced from residues taken from a palm cooking oil manufacturing process. It is found that the cetane number of B100 is almost 30% higher than that of B0 and this could be attributed to the oxygen content in the biofuel. Under similar thermal conditions at the start of injection, it is observed that the influence of engine load on premixed combustion is minimal. This could be attributable to the well-controlled intake air temperature in this special engine and therefore the evaporation and mixing rate prior to the start of combustion is similar under different loading conditions. Owing to higher cetane number (CN), B100 is more reactive and auto-ignites up to 3 degrees of crank angle (DCA) earlier compared to B0. It is generally observed in this study that B10 shows a higher maximum value of in-cylinder pressure compared to that of B0 and B20. This could be evidence for lubricant enhancement when operating the engine with low-blending ratio mixtures like B10 in this case.

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