Liquid organic hydrogen carriers (LOHC) are a promising form to store hydrogen. However, the process of dehydrogenation has to be demonstrated for applications with proton exchange membrane (PEM) fuel cells which require very pure hydrogen. Here we document the measured degradation effects due to CO contamination on a PEM fuel cell that is supplied with hydrogen from a LOHC and we want to use later in a maritime application.
Cell performance of formic acid/hydrogen peroxide (HCOOH/H2O2) fuel cell, using commercial Pt-Ru/C, and prepared Pt-M/C (M = Ir, Mo, Co, Ag, W, Ni, Sn) bimetallic catalysts as anode catalysts are experimentally investigated and reported in this paper. Corresponding to cell performance, electrocatalytic activity of the system using commercially available and prepared catalysts is evaluated by linear sweep voltammetry technique (LSV). The result shows that the system using 20%Pt-10%Sn/C yields better formic acid oxidation reaction than that of other Pt-M/C bimetallic catalysts, but it is inferior to that of 20%Pt-10%Ru/C commercial catalyst. In addition, the cell performance of HCOOH/H2O2 fuel cell with various catalyst compositions of Pt and Sn content, in portions of 10:20, 15:15, and 20:10, respectively, is also studied. Comparison among those catalysts, 15%Pt-15%Sn/C yields better cell performance than the others. Levelized energy cost (LEC) and sensitivity analysis on LEC are also assessed.
The article presents the problems related to the application of alternative fuel like solid biomass in the shipbuilding. The decreasing resources of the crude oil, the requirements regarding environmental protection as well as the increase of the liquid fuel prices were the reason for the study. The solid biomass comparing to the liquid or gaseous forms has relatively low calorific value. In order to increase this value the solid biomass is subject to the densification or torrefaction process and most often occurs in the shape of pellets. In this form it could be useful on ships. A test stand has been characterised where it can be experimentally verified whether ship’s rolling does affect the changes in flow resistance values during the pneumatic transportation of solid fuel from the storage facility to the boiler. On the basis of the measurements the hydraulic characteristics have been provided for the piping located on the movable platform with and without granular material. The changes in the platform oscillation period have influence on the change in the pressure inside transport piping for each investigated material. The results also show that the platform constantly inclinations do exert an influence on the pressure drop in the transport pipeline during transporting the granular material. It is smaller when the position is inclined. Comparing the results obtained for the different transported materials of a similar nature of the pressure fluctuations could be observed.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.