International audienceIn this work, NiP-SiC composite coatings were prepared by electrodeposition from a plating bath containing NiSO4*6H2O; NiCl2*6H2O; H3PO3; H3PO4; Na2 SO4 and SiC particles (average diameter of 600 nm) in suspension. Anionic surfactant (SDS -- sodium dodecyl sulfate, CH3 (CH2)11SO4Na) or cationic surfactant (CTAHS--cetyltrimethylammonium hidrogensulfate, C19H43NO4S) were also added to this suspension. The number of incorporated particles by area unit (αnp/A) was evaluated by image analysis of micrographs obtained by scanning electron microscopy SEM). It was observed that organic additive addition influences the incorporated SiC particles rate on the metallic matrix. Addition of organic additives such as SDS or CTAHS modifies the characteristic of suspensions. Depending on particle size organic additive addition can change the number of incorporated particles in deposits during growth of the matrix. Decrease of the incorporated particle amount with the increase of particle size was verified. The selective incorporation process is associated to the presence of organic additive and it was not dependent on surfactant charge

International audienceThis work aimed to study the corrosion behavior of AA2024-T3 aluminum alloy substrates pre-treated with 3 glicidoxypropyltrimethoxysilane (GPTMS) silane layers doped with different cerium ion concentrations. The withdrawal speed of substrates from the sol was 20 cm * min-1. The hybrid films were obtained by dip-coating process and analyzed by scanning electron microscopy (SEM) and energy dispersive spectroscopy, Rutherford scattering spectroscopy (RBS), salt spray test, and electrochemical analyses. The correlation among the results obtained from different analyses was very good and indicated that the addition of Ce ion in the hybrid coating contributed to the corrosion resistance; however, for the high Ce ion concentration, the barrier effect of the hybrid films was deteriorated. The results obtained by RBS showed that the concentration of Ce ion in the hybrid film increased linearly with the concentration of Ce ion in the sol. Moreover, it was verified that, for the nominal concentration of 0.05 M Ce ion in the sol, the Ce atomic fraction increased in the hybrid film, while the Si atomic fraction reduced, indicating the possible modification on the silane network due to the incorporation of Ce ions

This study proposes a new pretreatment method that uses alkoxide precursors with a plasticizing agent; the purpose of this study is to improve the electrochemical and mechanical properties of a galvanized steel surface. Galvanized steel was covered with a hybrid film obtained from a sol that consisted of two alkoxide precursors, 3 -(trimethoxysilylpropyl) methacrylate (TMSM) and tetraethoxysilane (TEOS), with nitrate cerium in a concentration of 0.01 M and a polyethylene glycol (PEG) plasticizer. The hybrid coatings were obtained by dip-coating method with various concentrations of plasticizer (0, 20, 40 and 60 g.L -1 ). The hybrid films were analyzed by scanning electron microscopy (SEM), profilometry, contact angle measurements, a tribometer with the type-setting ball on the plate and electrochemical tests. The addition of the plasticizer into the hybrid films improves the corrosion resistance behavior compared to the sample without the plasticizer. The addition of 20 g.L -1 of plasticizer showed the best performance in the electrochemical tests. The mechanical behavior results indicated that higher PEG concentrations resulted in films with enhanced durability.

Hybrid films obtained by a sol-gel process are based on two important reactions: hydrolysis and condensation. The condensation reaction is influenced by the curing temperature, since it induces the development of the intrinsic properties of the gel. The aim of this work is to coat tinplate, a substrate widely used in the packaging industry, with monolayered and bilayered hybrid films modified with polyethylene glycol and obtained through dip-coating. The results showed that the bilayered hybrid film obtained at 60°C had a higher layer thickness, and the best performance in the electrochemical assays, as well as the most hydrophobic character, in relation to the other samples. For the monolayered systems, the 90°C-cured system showed a lower layer thickness; however, this system showed a more compact, uniform and less porous layer, and presented better electrochemical impedance results, in comparison with the 60°C-cured samples.

The API 5CT P110 steel is employed in oil and gas industry due to its excellent mechanical properties. However, its poor corrosion resistance makes necessary the employment of a protection. Although nickel-based and cobalt-based coatings obtained by HVOF have been widely studied regarding corrosion resistance, they are normally associated with other elements. Pure nickel and/or pure cobalt HVOFobtained coatings have not yet been studied.Therefore, in this work, the corrosion resistance of nickel and cobalt coatings obtained by high-velocity oxy-fuel thermal spraying on API 5CT P110 steel was evaluated. The coatings were characterized regarding morphology and structure by SEM, EDS, XRD, roughness, and Vickers microhardness. The corrosion resistance was evaluated by OCP monitoring and potentiodynamic polarization in a 3.5 wt% sodium chloride solution. The results showed that both coatings acted as a barrier and avoided the contact between the steel substrate and the electrolyte due to the low melting point of the metals employed, which resulted in effective fusion of the particles. Besides, the nickel coating, promoted a better corrosion resistance compared to cobalt coating.