A facile interfacial synthesis strategy is proposed to synthesize self-assembled polypyrrole (PPy) free-standing films for electrochemical capacitors with the assistance of surfactants. The chemical structure of the obtained samples is characterized by Fourier transform infrared. The morphologies of the samples are studied by scanning electron microscope. The results show that the prepared PPy films own highly porous structures using Tween80 as a surfactant, while the synthesized PPy films have vesicular structures by adding Span80 as a surfactant. Furthermore, lowering polymerization temperature makes PPy films have smaller and more pores or vesicles. The PPy films prepared at 0 C with Tween80 as a surfactant possess a high specific capacitance of 261 F g 21 at 25 mV s 21 as well as retain 75% of the initial specific capacitance value after 1000 cycles. The good electrochemical properties can be attributed to the highly porous structural advantage of the PPy films caused by Tween80. V C 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015, 132, 41615.

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Due to the gas injection and production of underground salt caves during the operational phase, rock salt is often subjected to a combined stress of cyclic pressure and constant pressure. In order to investigate the damage evolution of rock salt under different combined stresses, the uniaxial cyclic loading test and cyclic creep test were carried out. The stress-strain curves, energy characteristics, energy dissipation, and damage of rock salt in the two experiments were analyzed and compared. The test results show that the stress-strain curves of the two tests presented three stages of “sparse”-“dense”-“sparse.” As the maximum stress increases, the stage of “dense” will decrease and the rock salt cycle life will decrease. The relationship between cycle life and Δσ (difference between maximum and minimum stress in the tests) is an exponential function under cyclic loading and a linear relationship under cyclic creep. Based on the experimental data, the energy dissipation of rock salt is analyzed. The damage variables were defined from the perspective of energy dissipation, and the damage evolution of rock salt under two tests was obtained. There are three corresponding stages of energy dissipation and damage: initial, constant speed, and acceleration. The damage model is obtained by inverse functioning the s function, and then the correction coefficient is added to the model to obtain the modified damage model. The modified damage model is compared with the experimental data. The results show that the model can accurately describe the three stages of rock salt damage. The significance of parameters in the modifying damage model is also discussed.

Uniaxial experiments were carried out on red sandstone specimens to investigate their short-term and creep mechanical behavior under incremental cyclic compressive and tensile loading. First, based on the results of short-term uniaxial incremental cyclic compressive and tensile loading experiments, deformation characteristics and energy dissipation were analyzed. The results show that the stress-strain curve of red sandstone has an obvious memory effect in the compressive and tensile loading stages. The strains at peak stresses and residual strains increase with the cycle number. Energy dissipation, defined as the area of the hysteresis loop in the stress-strain curves, increases nearly in a power function with the cycle number. Creep test of the red sandstone was also conducted. Results show that the creep curve under each compressive or tensile stress level can be divided into decay and steady stages, which cannot be described by the conventional Burgers model. Therefore, an improved Burgers creep model of rock material is constructed through viscoplastic mechanics, which agrees very well with the experimental results and can describe the creep behavior of red sandstone better than the Burgers creep model.