Abstract. As part of the 2019 Southern oCean seAsonal Experiment (SCALE) Winter Cruise of the South African icebreaker SA Agulhas II, first-year ice was sampled at the advancing outer edge of the Antarctic marginal ice zone along a 150 km Good Hope Line transect. Ice cores were extracted from four solitary pancake ice floes of 1.83–2.95 m diameter and 0.37–0.45 m thickness as well as a 12×4 m pancake ice floe of 0.31–0.76 m thickness that was part of a larger consolidated pack ice domain. The ice cores were subsequently analysed for temperature, salinity, texture, anisotropic elastic properties and compressive strength. All ice cores from both solitary pancake ice floes and consolidated pack ice exhibited predominantly granular textures. The vertical distributions of salinity, brine volume and mechanical properties were significantly different for the two ice types. High salinity values of 12.6±4.9 PSU were found at the topmost layer of the solitary pancake ice floes but not for the consolidated pack ice. The uniaxial compressive strengths for pancake ice and consolidated pack ice were determined as 2.3±0.5 and 4.1±0.9 MPa, respectively. Young's and shear moduli in the longitudinal core direction of solitary pancake ice were obtained as 3.7±2.0 and 1.3±0.7 GPa, respectively, and of consolidated pack ice as 6.4±1.6 and 2.3±0.6 GPa, respectively. Comparing Young's and shear moduli measured in longitudinal and transverse core directions, a clear directional dependency was found, in particular for the consolidated pack ice.

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Abstract. Sea ice is difficult, expensive, and potentially dangerous to observe in nature. The remoteness of the Arctic Ocean and Southern Ocean complicates sampling logistics, while the heterogeneous nature of sea ice and rapidly changing environmental conditions present challenges for conducting process studies. Here, we describe the Roland von Glasow Air-Sea-Ice Chamber (RvG-ASIC), a laboratory facility designed to reproduce polar processes and overcome some of these challenges. The RvG-ASIC is an open-topped 3.5 m3 glass tank housed in a cold room (temperature range: −55 to +30 ∘C). The RvG-ASIC is equipped with a wide suite of instruments for ocean, sea ice, and atmospheric measurements, as well as visible and UV lighting. The infrastructure, available instruments, and typical experimental protocols are described. To characterise some of the technical capabilities of our facility, we have quantified the timescale over which our chamber exchanges gas with the outside, τl=(0.66±0.07) d, and the mixing rate of our experimental ocean, τm=(4.2±0.1) min. Characterising our light field, we show that the light intensity across the tank varies by less than 10 % near the centre of the tank but drops to as low as 60 % of the maximum intensity in one corner. The temperature sensitivity of our light sources over the 400 to 700 nm range (PAR) is (0.028±0.003) W m−2 ∘C−1, with a maximum irradiance of 26.4 W m−2 at 0 ∘C; over the 320 to 380 nm range, it is (0.16±0.1) W m−2 ∘C−1, with a maximum irradiance of 5.6 W m−2 at 0 ∘C. We also present results characterising our experimental sea ice. The extinction coefficient for PAR varies from 3.7 to 6.1 m−1 when calculated from irradiance measurements exterior to the sea ice and from 4.4 to 6.2 m−1 when calculated from irradiance measurements within the sea ice. The bulk salinity of our experimental sea ice is measured using three techniques, modelled using a halo-dynamic one-dimensional (1D) gravity drainage model, and calculated from a salt and mass budget. The growth rate of our sea ice is between 2 and 4 cm d−1 for air temperatures of (-9.2±0.9) ∘C and (-26.6±0.9) ∘C. The PAR extinction coefficients, vertically integrated bulk salinities, and growth rates all lie within the range of previously reported comparable values for first-year sea ice. The vertically integrated bulk salinity and growth rates can be reproduced well by a 1D model. Taken together, the similarities between our laboratory sea ice and observations in nature, as well as our ability to reproduce our results with a model, give us confidence that sea ice grown in the RvG-ASIC is a good representation of natural sea ice.

This study presents the first dataset of physical and textural properties of sea ice collected in the South Atlantic and Indian Ocean sector of the Antarctic marginal ice zone (MIZ). Observations of sea ice from this region in the austral spring 2019, including sea-ice core temperature, salinity, crystal size, texture, oxygen isotopes and stratigraphy, were used in conjunction with a Lagrangian back-tracking algorithm and atmospheric reanalyses. This method relates the reconstructed synoptic conditions to sea-ice growth along the transect. A significant difference was found between the stratigraphy of consolidated pack ice samples collected at the same latitude and spanning over 550 km eastwards. The eastward group was found to have more disturbances in their stratigraphy which is attributed to the highly variable atmospheric and sea-ice conditions together with varying wave penetration through the sea-ice pack, notably during the passage of an intense polar cyclone, while the westward group showed no signs of disturbance or deformation. These results indicate that consolidated Antarctic sea-ice floes of similar thickness and from the same latitude in the MIZ have distinct stratigraphic properties, which will influence their physical and biogeochemical features.

In moving towards a greener global energy supply, hydrogen fuel cells are expected to play an increasingly significant role. New catalyst support materials are being sought with increased durability. MAX phases show promise as support materials due to their unique properties. The layered structure gives rise to various potential (001) surfaces. DFT is used to determine the most stable (001) surface terminations of Ti2AlC, Ti3AlC2 and Ti3SiC2. The electrical resistivities calculated using BoltzTraP2 show good agreement with the experimental values, with resistivities of 0.460  µΩ  m for Ti2AlC, 0.370  µΩ  m for Ti3AlC2 and 0.268  µΩ  m for Ti3SiC2. Surfaces with Al or Si at the surface and the corresponding Ti surface show the lowest cleavage energy of the different (001) surfaces. MAX phases could therefore be used as electrocatalyst support materials, with Ti3SiC2 showing the greatest potential.