Iron–copper bimetallic nanoparticles (Fe-Cu BNPs) were prepared via a green synthesis route. Ixora finlaysoniana has been used in this study as a capping and stabilizing agent in the modification of Fe-Cu BNPs. As-synthesized BNPs were characterized using different techniques including UV/Vis spectrophotometry, FTIR, XRD and SEM. A particle size analyzer and SEM studies indicated the particle size to be in the range of 50–200 nm. In addition, degradation of MB dye in an aqueous system and radical-scavenging potential in a DPPH assay were also examined using BNPs. Methylene blue dye degradation in 17 min was monitored with UV/Vis spectrophotometry, which exhibited the efficiency of Fe-Cu BNPs. Bimetallic nanoparticles were also found to be efficient in neutralizing DPPH free radicals. Furthermore, kinetic studies of both dye degradation and radical scavenging potential are reported in this article. Subsequently, Fe-Cu BNPs synthesized via a green and sustainable method can be employed for dye degradation and free radical-scavenging activities.
In the present study, biological method was opted to synthesize ZnO NPs from Rumex dentatus plant. 0.1 M solution of zinc nitrate hexahydrate is mixed with the aqueous solution of R. dentatus plant leaves extract. The proportion of each solution was 1:1. Extract of plant leaves act as reducing agent. Firstly, the color changed from dark green to brown was observed and precipitates of light brown color appeared. Characterization of produced ZnO NPs was done using UV–Visible spectroscopy, scanning electron microscopy (SEM), energy dispersive X-rays (EDX) and X-ray diffraction (XRD) spectroscopy. The prepared ZnO NPS shows maximum absorption at 373 nm, in UV–Visible range. The shape of synthesized ZnO NPs is displayed by SEM. XRD analysis explains the average size of NPs is 6.19 nm. EDX tells about the percentage composition of synthesized ZnO NPs. Antibacterial analysis declared the NPs as good antibacterial agents. Photocatalytic activity of ZnO NPs was done using methyl orange dye. It was concluded that ZnO NPs can degrade toxic pollutants especially dyes.
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