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Derivatives of lactames such as amide‐chlorides or lactame‐acetals, are synthesized in situ by the reaction of (I) with POCl3 or with (CH3)2SO4/NaOEt.

Supposing free‐fall conditions the velocity distribution functions of atoms and ions in various levels in gas discharges at low pressures are calculated. In particular, plasmas at high degrees of ionization are considered. Solving the Boltzmann equation for the motions transverse to the wall of the discharge tube it is shown that the velocity distribution functions can considerably deviate from the Maxwellian and become non‐isotropic. Inelastic collisions with electrons and the ionization by electron impacts considerably determine the velocity distribution function of the neutral atoms. The velocity distribution function of the ions is also essentially determined by the electric field within the plasma. For the motions transverse to the wall the half widths of the velocity distribution functions do not only depend on the temperature of the wall, but on the electron density and on the electron temperature as well. At small electron densities the half widths for excited atoms and for ions can be narrower than the one for the ground state atoms. The charge exchange between atoms and ions is shortly taken into consideration.