“Electronic nose” technology, including technical and software tools to analyze gas mixtures, is promising regarding the diagnosis of malignant neoplasms. This paper presents the research results of breath samples analysis from 59 people, including patients with a confirmed diagnosis of respiratory tract cancer. The research was carried out using a gas analytical system including a sampling device with 14 metal oxide sensors and a computer for data analysis. After digitization and preprocessing, the data were analyzed by a neural network with perceptron architecture. As a result, the accuracy of determining oncological disease was 81.85%, the sensitivity was 90.73%, and the specificity was 61.39%.
In this paper, we study the possibility of obtaining iron and titanium-vanadium concentrates with highest contents of iron and titanium, respectively, through hydrometallurgical processing of the titanomagnetite ores of the Chineisk deposit. We varied two key parameters to determine the efficiency of the process: (a) concentration of leaching solution (ammonium fluoride); and (b) acidity of solution. Ammonium fluoride concentration was varied from 0.08 mol/L to 4.2 mol/L with the other fixed parameters. It was shown that optimum ammonium fluoride concentration for leaching the ore is 0.42 mol/L; at these concentrations iron and titanium contents are about 62.8 wt % and 3.5 wt % in solid phase, respectively. The acidity of solution was changed by adding of hydrofluoric acid with varied concentration (from 0.86 mol/L to 4.07 mol/L) to ammonium fluoride solution with fixed concentration of 0.42 mol/L. The best results (degree of titanium extraction = 63.7%) were obtained when using a solution of hydrofluoric acid with concentration 4.07 mol/L. In this case, the addition of acid makes it possible to increase the Fe/Ti ratio by 3.4 times in comparison with the original ore. Thus, we conclude that acidity and the concentration of ammonium fluoride solution significantly influences the selectivity of the hydrometallurgical process.
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