Metal-based
antiperspirants have been in use for centuries; however,
there is an increasing consumer demand for a metal-free alternative
that works effectively. Here, we develop an artificial sweat duct
rig and demonstrate an alternative, metal-free approach to antiperspiration.
Instead of clogging sweat ducts with metal salts, we use a hygroscopic
material to induce the evaporation of sweat as it approaches the outlet
(i.e. pore) of the sweat duct. As a result, the sweat dehydrates almost
completely while still being inside of the duct, forming a natural
gel-like salt plug that halts the flow. We show that the critical
pressure gradient within the duct (∼3 kPa), beneath which clogging
occurs, can be rationalized by balancing the mass flow rates of the
liquid (Poiseuille’s law) and the evaporative vapor (Fick’s
law).
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