Introduction. The purpose of the paper is to study theoretical and experimental aspects of the chemical composition and quality of hemp seed products, including oxidation processes in oils, seeds and processing products. Materials and methods. Research materials are industrial hemp seeds of «Hlesiia» variety, pressed oil and oil compositions, hemp seeds kernel. The quality of the investigated materials was evaluated according to standard and industry methods and to Codex Alimentarius. Results and discussion. The obtained hemp oils by the content of fatty acids, phospholipids, vitamins A and E have high biological value, and by the content of tocopherols significantly outweigh sunflower, sesame and amaranth oils. The sample of MM60 pressed oil is preferred for antioxidant resistance. The ratio of essential fatty acids is close to ideal: Omega-6 and Omega-3 as 3.0:1-3.7:1, while in linseed oil-1:3.6. Hemp oil also contains biologically valuable gammalinolenic acid. Spectrophotometric method confirmed the presence of carotenoids and chlorophylls in pressed hemp oil. Vitamin A content in oil is 78 mg/kg, vitamin E (total)-562.8 mg/kg. Hemp oil is better stored at 8±2 °C without light access by chemical indicators. The obtained hemp oil and oil compositions are of good quality. The composition with a peroxide and acid value of less than 1 and a higher oil output is preferred. The quality of hemp seeds (without the shell) improves compared to the output seeds. The content of oil and protein increased 1.5 times, macro and microelements: phosphorus 1.5 times, ferro 1.25 times, zinc and cobalt 2 times. Hemp seeds without the shell have a high content of essential amino acids and a high content of lysine, which is usually deficient. Conclusions. It is recommended the hemp oil and hemp seeds kernel in the production of functional food.
As a result of alkaline neutralization of oils, a significant amount of soapstock is formed, the utilization of which creates an environmental and economic problem. The production of fatty acids from soapstock using sulfuric acid decomposition is investigated in this work. The peculiarity of the work is the determination of regression dependences of the yield and neutralization number of fatty acids on the soapstock processing conditions: temperature and duration. Soapstock obtained after neutralization of sunflower oil was used as raw material. Soapstock indicators: mass fraction of moisture – 15.4 %, total fat – 71.9 %, fatty acids – 64.5 %, neutral fat – 7.4 %. Rational conditions of soapstock processing are determined: temperature (90–95) °С, duration 40 min. Under these conditions, the fatty acid yield is 79.0 %, the neutralization number is 180.0 mg KOH/g. Quality indicators of the obtained fatty acids: mass fraction of moisture and volatile substances – 1.8 %, mass fraction of total fat – 97.0 %, cleavage depth – 64.5 % of oleic acid, the presence of mineral acids – no. Fatty acids correspond to fatty acids of the first grade according to DSTU 4860 (CAS 61788-66-7). An increase in the temperature and duration of soapstock contact with sulfuric acid increases the yield and neutralization number of fatty acids. This is due to a decrease in the viscosity of the reaction medium, an increase in the depth of cleavage of soapstock soaps with sulfuric acid, an increase in the intensity and duration of mass transfer. The developed rational conditions allow obtaining fatty acids from soapstock, which correspond in composition to fatty acids from refined deodorized sunflower oil. The results allow solving a number of economic and environmental problems associated with soapstock utilization and can be implemented in oil refineries and fatty acid production
The processing of oil refining waste is essential from economic and environmental points of view. An important issue is the processing of soapstock to extract fatty acids, which are raw materials for various industries. The two-stage method of fatty acids obtaining from soapstock using saponification with sodium hydroxide solution and decomposition with sulfuric acid is investigated. The peculiarity of the work is the study of the influence of soapstock saponification conditions on the key efficiency indicators of fatty acid extraction: yield and neutralization number. A sample of soapstock was obtained as a result of alkaline neutralization of sunflower oil. Soapstock quality corresponds to DSTU 5033 (CAS 68952-95-4): mass fraction of total fat – 68.5 %, fatty acids – 62.6 %, neutral fat – 5.9 %. Rational saponification conditions were determined: duration (85 min.) and concentration of sodium hydroxide solution (45 %). After saponification, the soapstock was subjected to decomposition with sulfuric acid under the following conditions: temperature 90 °C, duration 40 min. Under the rational saponification conditions, the yield of fatty acids (91.8 %) and the neutralization number (187.1 mg KOH/g) were determined. The obtained fatty acids correspond to the first-grade fatty acids according to DSTU 4860 (CAS 61788-66-7). Acid indicators: mass fraction of moisture and volatile substances – 1.5 %, mass fraction of total fat – 98.0 %, cleavage depth – 69.2 % oleic acid. The use of the soapstock saponification stage before decomposition leads to an improvement in the quality indicators and an increase in the neutralization number of fatty acids by 4 %, yield – by 16.2 %. The results of the study make it possible to produce fatty acids from soapstock by two-stage technology with high yield and neutralization number
The paper considers the way to solve the problem of processing waste from the oil and fat industry, namely sunflower and soybean meals, which are a source of many valuable substances. The peculiarity of the work lies in determining the rational ratio of the base components of extruded animal feed, which is an important aspect of obtaining high-quality competitive products. The research object is the use of oil and fat industry waste in extruded animal feed technology. The rational ratio of the components of extruded animal feed has been determined. The rational ratio of animal feed components is: sunflower meal – 0.40 parts by weight; soybean meal – 0.25 parts by weight; oatmeal – 0.35 parts by weight. The animal feed sample with justified composition corresponds to the commercial analogue in terms of porosity (72 % and 76 %, respectively) and cost ($285/t and $285/t, respectively). In addition, the extruded feed with the developed composition exceeds the commercial analogue in terms of protein content by 3.2 times and essential amino acids content by 2.9 times. The obtained data are explained by the use of a complex of components, namely oil and fat waste and starch-containing grain raw materials with various limiting amino acids and various technological features of the extruded mass of their mixture. The feature of the obtained results is the possibility to control the technological characteristic (porosity) of the finished product depending on the components ratio, which allows changing product characteristics according to consumer requirements. The research results make it possible to efficiently process secondary products of oilseed processing into a new competitive marketable product. From a practical point of view, the technology makes it possible to reduce the cost of storage/utilization of industry waste, get additional income from new products sales and improve environmental conditions. The applied aspect of using the scientific result is the possibility to create a range of animal feed with different technological indicators depending on the components ratio.
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