Maritime transport is investigating several options to reduce its greenhouse gases and air pollutant emissions. An experimental ship, Energy Observer, is using excess renewable energy to generate onboard hydrogen by electrolysis of purified seawater. As a promising option for storing energy, it can provide on-demand energy to the ship through a hydrogen fuel cell (FC). As hydrogen FCs lifetime and performance are correlated to hydrogen quality, the hydrogen produced onboard needs to be monitored. This study assesses the probability of contaminants presence for this electrolyser, using purified seawater and supports the results with a hydrogen fuel quality analysis from the Energy Observer ship. It demonstrates that an electrolyser using onboard purified seawater can generate hydrogen of a quality compliant with ISO 14687:2019. Additional contaminants (i.e., ions, heavy metal) were also measured. The study highlights the potential contaminants to be monitored and future research on new contaminants from seawater to further develop hydrogen fuel for maritime applications.

Fuel cell electric vehicles (FCEV) are developing quickly from passenger vehicles to trucks or fork-lifts. Policymakers are supporting an ambitious strategy to deploy fuel cell electrical vehicles with infrastructure as hydrogen refueling stations (HRS) as the European Green deal for Europe. The hydrogen fuel quality according to international standard as ISO 14687 is critical to ensure the FCEV performance and that poor hydrogen quality may not cause FCEV loss of performance. However, the sampling system is only available for nozzle sampling at HRS. If a FCEV may show a lack of performance, there is currently no methodology to sample hydrogen fuel from a FCEV itself. It would support the investigation to determine if hydrogen fuel may have caused any performance loss. This article presents the first FCEV sampling system and its comparison with the hydrogen fuel sampling from the HRS nozzle (as requested by international standard ISO 14687). The results showed good agreement with the hydrogen fuel sample. The results demonstrate that the prototype developed provides representative samples from the FCEV and can be an alternative to determine hydrogen fuel quality. The prototype will require improvements and a larger sampling campaign.