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Activity levels of natural and artificial radionuclides and content of ten heavy metals (As, Cd, Co, Cr, Cu, Mn, Ni, Pb, Zn and Hg) were investigated in 41 soil samples collected from Toplica region located in the south part of Serbia. Radioactivity was determined by gamma spectrometry using HPGe detector. The obtained mean activity concentrations ± standard deviations of radionuclides Ra,Th, K andCs were 29.9 ± 9.4, 36.6 ± 11.5, 492 ± 181 and 13.4 ± 18.7 Bq kg, respectively. According to Shapiro-Wilk normality test, activity concentrations of Ra andTh were consistent with normal distribution. External exposure from radioactivity was estimated through dose and radiation risk assessments. Concentrations of heavy metals were measured by using ICP-OES, and their health risks were then determined. Enrichment by heavy metals and pollution level in soils were evaluated using the enrichment factor, the geoaccumulation index (I), pollution index and pollution load index. Based on GIS approach, the spatial distribution maps of radionuclides and heavy metal contents were made. Spearman correlation coefficient was used for correlation analysis between radionuclide activity concentrations and heavy metal contents.

Bio-climatological analysis of Vranjska spa, based upon the equivalent temperatures (Teq) and Charles method (vapor weight), along with anthropo-climatic classification of Kruger, updated and adjusted, served as means of determining bio-climatological characteristics. Equivalent temperatures have been calculated for the period between 1985 and 2005, for the meteorological station Vranje, placed into six bio-climatological classes and three weather types. Representative weather types are cold (5.0 °C < Теq < 22.0 °C), agreeable (22.0 °C < Теq < 50.0 °C) and overheated (50.0 °C < Теq < 70.0 °C) with following classes: cold, algid, cool, agreeable, warm, humid and sultry.

The monitoring of the territory of Prokuplje Municipality was done based on 1 : 25,000 topographic maps in three different time periods (1969, 1974, and 1984) and land cover map in 2012. Analogous topographic maps done in 1969, 1974, and 1984 were used, while in 2012 the land cover map obtained by using CORINE-like approach was used. Topographic maps are developed by aerial campaign, and today they are replaced by satellite images. Topographic maps were scanned, and raster form was transformed to vector data with Geo Media Professional 6.1 and Global Mapper software. The monitoring in the period of 1969–2012, on the area of 758300000 m2, was performed, where some parameters were analyzed. In particular, the changes of natural resources, primarily forest lands, were observed as well as the type of land susceptible to primary erosion, including the level of urbanization and level of agricultural land. The obtained results clearly showed changes in forestation within the 43-year-long period, as well as changes in primary erosion and urbanization, while at the level of agricultural land, slight changes were found. The paper also involved transition of social factors from 1969 to 2012, expressed as a change between the earth and forest layer.