Measurements have been made of the ultrasonic velocity in thirty-four organic liquids over a temperature range of 0−60°C by use of a variable-path ultrasonic interferometer operating at 500,000 cycles per second. For all of the liquids studied the relation between velocity and temperature was found to be essentially linear. Values of density, adiabatic compressibility, and temperature coefficient (ΔV/ΔT) are also reported. It was found that the successive substitution of a heavier atom in a molecule leads to successively smaller temperature coefficients. It is pointed out that the temperature coefficient of ultrasonic velocity appears to be inversely proportional to the square root of the molecular weight, to a fair degree of accuracy.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.