Implementation of Principles of Green Chemistry in teaching chemistry can become an essential approach to enhance students' awareness of environmental problem. In contrast with the goal of sustainability, chemistry practicum normally deals with chemicals and waste management which contribute to environmental problem. A shift toward more sustainable and economical experiments is essential to maintain the existence of the practicum in senior high curriculum. Small Scale Chemistry (SSC) practicum is one of the approaches to promote sustainability in chemistry practicum by using smaller scale and safer apparatus. It is expected to produce less waste. It is also safer and more economical chemistry experiment. This research aims to study the integration of principles of green chemistry in chemistry practicum by using SSC experiment. This study investigates two main topics in senior high school chemistry subject: electrochemistry and acid-base indicator. This study has shown the practice of integration of the principles of green chemistry approach into senior high school chemistry practicum through SSC. The experiments demonstrated in this study enable us to integrate Principles of Green Chemistry in terms of preventing waste, using less hazardous chemical, and conducting safer experiments which can be implemented in senior high school chemistry practicum.
The immobilized cell using self-assembled synthetic oligopeptide was applied to the electrochemical detection of pathogen infection. Thin films based on cysteine-terminated synthetic oligopeptides were fabricated for the immobilization of HeLa cell on gold (Au) substrate. Layer formation and immobilization of the cell were investigated with surface plasmon resonance (SPR) and electrochemical impedance spectroscopy (EIS). Experimental results showed that the thin film of cysteine-terminated synthetic oligopeptide was successfully fabricated and it could be applied for the immobilization of HeLa cells. The adhered living cell was exposed to E. coli O157:H7, which induced the change of SPR angle and electrochemical impedance signal. The proposed cell immobilization method using self-assembly technique can be applied to construct the cell microarray for on-site pathogen monitoring.
Smart city and innovative building strategies are becoming increasingly more necessary because advancing a sustainable building system is regarded as a promising solution to overcome the depleting water and energy. However, current sustainable building systems mainly focus on energy saving and miss a holistic integration of water regeneration and energy generation. Here, we present a theoretical study of a solar optics-based active panel (SOAP) that enables both solar energy storage and photothermal disinfection of greywater simultaneously. Solar collector efficiency of energy storage and disinfection rate of greywater have been investigated. Due to the light focusing by microlens, the solar collector efficiency is enhanced from 25% to 65%, compared to that without the microlens. The simulation of greywater sterilization shows that 100% disinfection can be accomplished by our SOAP for different types of bacteria including Escherichia coli. Numerical simulation reveals that our SOAP as a lab-on-a-wall system can resolve the water and energy problem in future sustainable building systems. Published by AIP Publishing. [http://dx
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