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The present study aims at providing insights into shock wave interference patterns in gas flows when a mixture different than air is considered. High-energy non-equilibrium flows of air and $$\hbox {CO}_2$$ CO 2 –$$\hbox {N}_2$$ N 2 over a double-wedge geometry are studied numerically. The impact of freestream temperature on the non-equilibrium shock interaction patterns is investigated by simulating two different sets of freestream conditions. To this purpose, the SU2 solver has been extended to account for the conservation of chemical species as well as multiple energies and coupled to the Mutation++ library (Multicomponent Thermodynamic And Transport properties for IONized gases in C++) that provides all the necessary thermochemical properties of the mixture and chemical species. An analysis of the shock interference patterns is presented with respect to the existing taxonomy of interactions. A comparison between calorically perfect ideal gas and non-equilibrium simulations confirms that non-equilibrium effects greatly influence the shock interaction patterns. When thermochemical relaxation is considered, a type VI interaction is obtained for the $$\hbox {CO}_2$$ CO 2 -dominated flow, for both freestream temperatures of 300 K and 1000 K; for air, a type V six-shock interaction and a type VI interaction are obtained, respectively. We conclude that the increase in freestream temperature has a large impact on the shock interaction pattern of the air flow, whereas for the $$\hbox {CO}_2$$ CO 2 –$$\hbox {N}_2$$ N 2 flow the pattern does not change.

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SU2-NEMO, a recent extension of the open-source SU2 multiphysics suite’s set of physical models and code architecture, is presented with the aim of introducing its enhanced capabilities in addressing high-enthalpy and high-Mach number flows. This paper discusses the thermal nonequilibrium and finite-rate chemistry models adopted, including a link to the Mutation++ physio-chemical library. Further, the paper discusses how the software architecture has been designed to ensure modularity, incorporating the ability to introduce additional models in an efficient manner. A review of the numerical formulation and the discretization schemes utilized for the convective fluxes is also presented. Several test cases in two- and three-dimensions are examined for validation purposes and to illustrate the performance of the solver in addressing complex nonequilibrium flows.

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