Herein, we first propose a method
to enhance the cyclic properties
of nickel-oxide-based electrochromic (EC) film established on a flexible
polyethylene terephthalate (PET) substrate. In this work, a zinc tin
oxide (ZTO) layer with a thickness of 18 nm was sputtered on the surface
of 120 nm thickness Si–Li codoped nickel oxide film, and then
XPS, XRD, SEM, electrochemical analysis, and a mechanical bending
test were used to explore the composition, structure, electrochemical
properties, and bending durability. The results show that the introduction
of a ZTO buffer layer can effectively get rid of the collapsed phenomenon
and grain coarsening of the nanocolumn microstructure during EC processing,
improving the attenuation of color transmittance (T
c) and optical modulation (ΔT).
After 600 electrochemical cycles, the T
c of the film at the wavelength of 550 nm decreased from 54.3% to
50.0%, and the ΔT increased from 28.6% to 35.5%,
which is superior to the one without the ZTO buffer layer after 600
electrochemical cycles (61.9% T
c and 22.8%
ΔT). In addition, the ZTO buffer layer can
also ensure the film has an enlarged charge capacity, rapid transport
speed of lithium ion for faster EC response, and admirable bendability.
This stability makes the double-layer structure promising for commercial
applications in future high-performance EC devices.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.