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The traditional hematite depressant starch has the disadvantages of poor solubility and high viscosity. In this study, a novel hematite depressant, pullulan, with better performance and flotation effect than starch was found. The structure, molecular weight and viscosity of pullulan were determined for its characterization. The results of flotation tests revealed that the flotation separation of hematite-quartz by pullulan was better than that of starch for hematite-quartz. The selective depression mechanism of pullulan on hematite was studied by contact angle measurement, zeta potential measurement, FT-IR analyses and XPS analyses. Overall, the weak adsorption of pullulan on quartz did not affect the adsorption of DOPA on the quartz surface. However, it was adsorbed strongly on hematite surface and hindered the adsorption of DOPA. This selective adsorption led to a much greater hydrophobicity of quartz than hematite in the reverse flotation, resulting in the separation of quartz and hematite. Pullulan was adsorbed by chemical bonding between its hydroxyl group and iron sites on the hematite surface. Thus, compared with starch, pullulan was easy to dissolve in water, had low viscosity and good flotation effect, so it was a better hematite depressant.

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