Piezocatalysis is a promising technology to address environmental pollution by converting mechanical energy into chemical energy. Herein, MoSe 2 nanosheets with different 1T phase percentages (ranging from 30 to 80%) were constructed by adjusting hydrothermal temperature. Moreover, the roles of phase engineering in the piezocatalysis were thoroughly investigated by degrading rhodamine B and reducing Cr(VI) in ultrasonic vibration conditions. In particular, MoSe 2 prepared at 220 °C (MoSe 2 -220) exhibits ultrahigh observed constant k obs and degradation rate k, which is superior to most reported catalysts to date. The experimental results indicate that the introduction of the 1T phase increases the active sites of the material, improves the conductivity, and inhibits the recombination of electrons and holes. Moreover, an internal electric field in the 2H phase induced by piezoelectric polarization is facilitated to separate electron−hole pairs, enabling the degradation and reduction to proceed. The capture experiments and EPR tests further confirm that • O 2 − and • OH are main reactive species, and a rational mechanism is finally put forward. This study offers a clear understanding of phase engineering in piezocatalysis and provides an efficiency strategy to construct highly efficient piezocatalysts.
Carbon fiber-reinforced polymer (CFRP)-confined foam concrete can be applied in structure protection, e.g., as an impact barrier of bridge piers, in which it is used as the core of the composite impact barrier. Applying CFRP to the foam concrete exterior enhances both the CFRP and the foam concrete, leading to improved compressive performance due to their interaction. In the present study, the carbon-fiber reinforced polymer (CFRP) confining effect on the response and energy absorption of foam concrete subjected to quasi-static and medium-strain-rate dynamic compression was experimentally investigated. The confinement by CFRP changed the response and failure mode of foam concrete specimens from shear in quasi-static load and splitting in dynamic load to crushing, resulting in a significant increase in the load bearing and energy absorption capacity. The composite consisting of CFRP and foam concrete was sensitive to strain rate. In particular, the CFRP–foam concrete interaction led to the remarkably improved resistance and energy absorption capacity of CFRP-confined specimens, which were significantly higher than the sum of those of standalone CFRP and foam concrete.
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