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There is currently a growing demand for more effective thermal insulation materials with the best performance properties. This research paper presents the investigation results on the influence of two types of filler on the structure and properties of rigid polyurethane foam composites. Fly ash as a product of coal combustion in power plants and microspheres of 5, 10, 15, and 20 wt.%, were used as rigid polyurethane foams modifiers. The results of thermal analysis, mechanical properties testing, and cellular structure investigation performed for polyurethane composites show that the addition of fly ash, up to 10 wt.%, significantly improved the majority of the tested parameters. The use of up to 20 wt.% of microspheres improves the mechanical and thermal properties and thermal stability of rigid polyurethane foams.

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This work focuses on the impact of carrier gas on the quantity and quality of pyrolytic products received from intermediate pyrolysis of the brewer’s spent grain. In this study, three types of carrier gases were tested: argon, nitrogen, and carbon dioxide at three temperatures of 500, 600, and 700 °C. On the basis of the process conditions, the yield of products was determined. The ultimate analysis of the char was performed, and for selected chars, the combustion properties were determined. Gas chromatography of the organic fraction of oil was performed, and the compounds were determined. Additionally, microscale investigation of the spent grain pyrolysis was performed by thermogravimetric analysis. The results showed that there were no significant differences in product yields in various atmospheres. Char yield changed only with temperature from 28% at 500 °C up to 19% at 700 °C. According to ultimate analysis, the char from CO2 pyrolysis was approximately 2% richer in carbon and this fact did not influence on the combustion properties of the char. The oil fraction was characterized mainly by acids with a maximum content of 68% at 600 °C in an argon atmosphere and the acid concentration depended on the carrier gas as follows line: Ar > N2 > CO2.

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